Question

In: Chemistry

When light of wavelength 420 nm strikes a metal surface, photoelectrons having a kinetic energy of...

When light of wavelength 420 nm strikes a metal surface, photoelectrons having a kinetic energy of 6.0 x 10-20 J are released.

a) What is the energy needed to remove an electron from the metal atom?

b) How much total energy would be needed to remove an electron from a mole of these metal atoms?

c) How many moles of photons would be required in part (b)?

Solutions

Expert Solution

use, for energy when wavelength is given

E = (h*C)/(wavelength)

value of planck constant h = 6.6*10-34 (J*s)

wavelength = 420 nm

= 420*10-9 m

= 42*10-8 m

E = (6.6*10-34*3*108)/(42*10-8)

E = (19.8*10-26)/(42*10-8)

E = (0.47*10-18) J

E = (47*10-20) J

a)

use,

K.E = E - (energy required)

6*10-20 = 47*10-20 - (energy required)

energy required = 47*10-20 - 6*10-20

energy required =41*10-20 J

b)

1 mole of any substances has 6.02*10 23 atom

1 atom require 41*10-20 J

6.02*1023 atom require (6.02*1023 *41*10-20) J

energy require for 1 mole of atom = (6.02*1023 *41*10-20) J

energy require for 1 mole of atom = (246.8*103) J

c)

n*(energy of one photon) =  (246.8*103) J

n*E =  (246.8*103) J

n*(47*10-20) J = (246.8*103) J

n = 5.25*1023


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