Write the IUPAC name for each of the following compounds: a. [Cr(NH3)5Cl]2+ b. [W(NH3)3(H2O)3]2+ c. [Fe(H2O)6]3+

Write the IUPAC name for each of the following compounds:

a. [Cr(NH₃)₅Cl]²⁺

b. [W(NH₃)₃(H₂O)₃]²⁺

c. [Fe(H₂O)₆]³⁺

Solutions

Expert Solution

[Cr(NH₃)₅Cl]²⁺

The coordination entity is positive, hence central metal atom is written as chromium.

ligands are ammine and chloro, alphabetically ammine is written before chloro, as 5 ammine groups are present therefore prefix penta is added.

ammine is neutral ligand, charge of chloro is -1 .

then, oxidation state of Cr = - 5 + 2 = + 3

hence IUPAC name is

Pentaamminechlorochromium (III) ion.

[W(NH₃)₃(H₂O)₃]²⁺

The coordination entity is positive, hence central metal atom is written as tungsten.

ligands are ammine (NH₃) and aqua (H₂O), alphabetically ammine is written before aqua, as 3 ammine groups and 3 aqua groups are present therefore prefix tri is added before both ligands.

ammine and aqua both are neutral ligands.

oxidation state of W = +2.

Hence IUPAC name is

Triamminetriaquatungsten (II) ion .

[Fe(H₂O)₆]⁺³

The coordination entity is positive , hence central metal atom is written as iron.

ligand is aqua (H₂O), six aqua is present, hence hexa is added as prefix.

aqua is neutral ligand, hence oxidation state of iron = +3

IUPAC name is Hexaaquairon (III) ion .

queen_honey_blossom answered 3 months ago

Next > < Previous

Related Solutions

For compounds, [Cr(H2O)6]Cl3 ; [Cr(H2O)5Cl]Cl2.H2O& [Cr(H2O)5Cl2]Cl.2H2O answer the following questions: - A....

For compounds, [Cr(H2O)6]Cl3 ; [Cr(H2O)5Cl]Cl2.H2O& [Cr(H2O)5Cl2]Cl.2H2O answer the following questions: - A. B. C. D. Does not lose water on H2SO4 - A. B. C. D. Loses one H2O on H2SO4 - A. B. C. D. Loses two H2O on H2SO4 - A....

What is the formal name for each of the following coordination compounds? a. [Co(H2O)3(NH3)3](NO3)3 b. Na3[FeF6]...

What is the formal name for each of the following coordination compounds? a. [Co(H2O)3(NH3)3](NO3)3 b. Na3[FeF6] c. [Mn(en)2Br2]Cl2 d. Ba[Sn(OH)4]

Give the names and charges of the cation and anion in each of the following compounds: (a) CaO, (b) Na2SO4, (c) KClO4, (d) Fe(NO3)2, (e) Cr(OH)3.

Which of the following compounds has the highest pka? a. NH3 b. H2O c. HCl d....

Which of the following compounds has the highest pka? a. NH3 b. H2O c. HCl d. CH4

Classify each of the following coordination compounds according to the coordination number. [CuCl2]-, [AlCl4]-, [Cr(CO)6], [Ag(NH3)2]+,...

Classify each of the following coordination compounds according to the coordination number. [CuCl2]-, [AlCl4]-, [Cr(CO)6], [Ag(NH3)2]+, [HgI3]-, Ba[FaBr4]2, K3[CoF6], [Fe(CO)5] The oxidation state is for the central metal atom in [Ni(CN)5]3–.

What is the coordination number for each of the following complexes or compounds? [Co(NH3)4(H2O)2]3+[Co(NH3)4(H2O)2]3+ [Mg(EDTA)]2−[Mg(EDTA)]2− [Cu(NH3)4]2+[Cu(NH3)4]2+...

What is the coordination number for each of the following complexes or compounds? [Co(NH3)4(H2O)2]3+[Co(NH3)4(H2O)2]3+ [Mg(EDTA)]2−[Mg(EDTA)]2− [Cu(NH3)4]2+[Cu(NH3)4]2+ [Ag(NH3)2]NO3[Ag(NH3)2]NO3 Enter the coordination numbers, in the order that the complexes are listed, as four integers separated by commas (e.g., 1,2,3,4). View Available Hint(s) Submit Part B What is the charge on each of the following complex ions? hexaaquamanganese(II), [Mn(H2O)6]?[Mn(H2O)6]? tris(carbonato)cobaltate(III), [Co(CO3)3]?[Co(CO3)3]? amminepentabromoplatinate(IV), [Pt(NH3)Br5]?[Pt(NH3)Br5]? Express the charges numerically, in the order that the complexes are listed, separated by commas. For a nonzero charge, be...

For each of the transition metal complex ions (a) [Ti(NH3)6]2+ (b) [Cr(H2O)4(OH)2]1- (c) trans–[Pt(CN)2(en)2]2+ (i) Draw...

For each of the transition metal complex ions (a) [Ti(NH3)6]2+ (b) [Cr(H2O)4(OH)2]1- (c) trans–[Pt(CN)2(en)2]2+ (i) Draw the structure of the transition metal complex ion. Show the charge on the complex. (ii) Determine the number of d electrons. (iii) Draw the ground state arrangement of the d electrons in the ground state. (iv) Calculate the LFSE (in units of Δo or ΔT) for each complex.

Please give the Correct IUPAC names of the following molecules (A) Pt(NH3)2ClBr (B) [Sr(H2O)8](ClO4)2 (C) Hf(acac)4...

Please give the Correct IUPAC names of the following molecules (A) Pt(NH3)2ClBr (B) [Sr(H2O)8](ClO4)2 (C) Hf(acac)4 (D) Rh(H2O)3Cl3 (E) [Co(H2O)2(NH3)2(SCN)I]Br (F) [Ni(en)2(NH3)4]SO4 (G) [Fe(en)3](NO2)2 (H) Na3[Co(CN)6] (I) Ba3[OsCl6]2 (J) (NH4)3[MoBr6] (K) (NMe4)2[AuCl6] (L) (PEt4)[Ag(CN)2]

Which has the greater octahedral field splitting energy? (Δo) [Cr(H2O)6]2+ or [Cr(H2O)6]3+ Blank 1. Fill in...

Which has the greater octahedral field splitting energy? (Δo) [Cr(H2O)6]2+ or [Cr(H2O)6]3+ Blank 1. Fill in the blank, read surrounding text. [Fe(NO2)6]3- or [FeCl6]3- Blank 2. Fill in the blank, read surrounding text. (Please Note: There was typo that was corrected in the formula. If you answered using either [Fe(NO2)6]2+ or [Fe(Cl6)6]2+ and were correct, you will still receive full credit). Na4[V(CN)4(OH)2] or Na4[Ta(CN)4(OH)2]

Using the initial concentrations of [Fe(H2O)6]^3+, SCN^-, and the equilibrium concentration of the [Fe(H2O)5SCN]^2+ complex, calculate...

Using the initial concentrations of [Fe(H2O)6]^3+, SCN^-, and the equilibrium concentration of the [Fe(H2O)5SCN]^2+ complex, calculate the equilibrium concentrations of both [Fe(H2O)6]^3+ and SCN^-. All mol/L. Ice table is needed. Initial concentrations of [Fe(H2O)6^3+: Initial concentrations of SCN: [Fe(H2O)5SCN]^2+ equilibrium: Fe(H2O)6 - SCN - EQ Fe(H2O)5SCN 0.390 1.54 23.42 0.390 3.12 35.99 0.390 4.84 58.09 0.390 6.25 74.81 0.390 7.96 98.97

Subjects