In: Chemistry
Question 1
The lines observed in H-lamp are parts of Balmer Series. All these lines are due to a transition from various higher n value to a common n. What is this common lower n value for all these lines?
0 |
1 |
2 |
3 |
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Question 2
The bright violet line of Hg lamp has a wavelength of 435.8 nm. What is the energy of the photon associated with this emission line?
4.56*10^-19 J |
4.56*10^-28 J |
6.88*10^14 J |
2.89*10^-31 J |
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Question 3
Given: In Atomic Spectra lab, a student obtained his best-fit line equation to be y = 0.29 x + 46.8 when he plotted his Vernier reading on the y-axis and wavelength in nm on the x-axis.
Question: If the Vernier reading for a line is 185.4, what is the predicted wavelength of this line in nm? (Keep 4 sig figs with one decimal place.)
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Question 4
The only electron in a hydrogen atom moved from n=2 to n=6. What is the wavelength of photon (in nm) being associated with this transition? Use whole numbers of nm without any decimal places, such as "415", "1125".
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Question 5
Which of the following transitions in a hydrogen atom will absorb the highest amount of energy?
n = 5 to n = 1 |
n = 1 to n = 2 |
n = 2 to n = 100 |
n = 10 to n = 10000 |
1).
In layman series electron goes upto principle number n = 1
In this case n = 1 is the final for layman series.
So the answer is 1
2).
Energy (E) = hc/l
h is planks constant = 6.626 E-34 Js ,c is speed of light = 3.0 E8 m/s
lets convert l into m
l= 435.8 nm x 1 E-9 m / 1 nm
= 4.36 E-7 m
Lets put these value to get E
E = 6.626E-34 Js x 3.0 E8 m/s / 4.36 E-7 m
= 4.56E-19 J
Energy per photon = 4.56 E-19 J
Question 3
Equation
y = 0.29 x + 46.8
185.4 = 0.29 x + 46.8
Lets find x
0.29 x = 138.6
x = 477.9 nm
wavelength = 477.9 nm
Question 4
Lets use Rydberg equation to calculate lambda
1/l= RH ( 1/ 22 – 1/62 )
RH is Rydberg constant = 1.097 E7 per m
Lets plug given values
1/ l= 1.097 E7 per m x ( ¼ - 1/36 )
l= 4.10 E-7 m
l in nm
= 1.40 E-7 x 1E9 nm / 1m
= 410 nm
Question 5 )
The final value should be large in order to get higher number in the bracket.
In given n=10 and n = 10000 the bracket value will higher as compare to other so the pair n = 10 (initial) and n =10000 final will absorb higher energy.