In: Chemistry
What is the probability of finding the particle in the region a/4 < x < a/2? show your work.
The probability of finding the particle in the region a/4 < x < a/2
The probability of particle in given range is given by *dx = 2dx-------------------(1)
In 1-D Particle =(2/a)1/2 sin[nπx/a]
lower limit is a/4 upper limit is a/2
*dx = 2dx= (2/a)sin2[nπx/a]dx sin2 x= (1-cos2x/2)
=2/a[1-cos2(nπx/a)]dx
= 2/a{1/2[1 dx] - [cos2(nπx/a) dx]}
= 2/a{1/2[x]a/2a/4 - a/[2nπ] [sin2(nπx/a)/]a/4a/2}
= 2/a{1/2[a/4-a/2] - a/[2nπ] [sin(2nπa/4 1/a)/]-[sin(2nπa/2 1/a]}
= (2/a )1/2{[a/4] - a/[2nπ] [sin(nπ)/]-[sin(nπ/2]}
= (2/a)(1/2){(a/4)- [a/2nπ][-(-1)n] }
= (2/a)(1/2){(a/4)- [a/2nπ][-(-1)n] }
= (2/a)(a/4){[1/2+(1/nπ) (-1)n]}
=1/2{(1/2) +(1/nπ)(-1)n}
probability P ={(1/4) +(1/2nπ)(-1)n}
for ground state i.e n=0
P= 1/4=0.25
For first excited state i,e n=1
P= [(1/4) -(1/2π)]