When chlorine is used for disinfection of drinking water,
chloroform can be produced by the reaction...
When chlorine is used for disinfection of drinking water,
chloroform can be produced by the reaction of chlorine with
residual organics in the water. For chloroform, RfDoral
= 0.01 mg/kg/d and SForal = 0.0061 1/(mg/kg/d).
Estimate the ingestion intake rate for non-carcinogenic and
carcinogenic effects on an adult resident of a home receiving tap
water with an average chloroform concentration of 65 mg/L.
Calculate the potential non-carcinogenic and carcinogenic
health risks associated with this ingestion rate.
Are the risks presented considered acceptable by the EPA?
When Chlorine gas is used to disinfect drinking water, it
hydrolyzes with the water to form hypochlorous acid (HOCl, pKa =
7.54), which is a powerful disinfectant. However, when the acid
dissociates to its conjugate base, it becomes a less effective
disinfectant. The disinfection power of the acid is 88 times better
than its conjugate base, OCl-, on a per-mole basis.
Calculate the mass of hypochlorous acid you would need to add
to 1 liter of water at pH =...
A CMFR will be used to reduce the concentration of
chloroform(CHCl3) in water. Chloroform is a disinfection by-product
that is formed when chlorine is used to disinfect water; it is a
concern because it can cause cancer.The influent water contains 60
ppb chloroform and the Wisconsin State standard is 6 ppb.
Chloroform decays in the reactor at a rate of 0.2 hr-1
and the water flow rate is 100 L/day.
Treating the water to meet the Wisconsin standard will reduce...
Define disinfection process, write the equations for the
dissolution (hydrolysis) of chlorine gas in water and the
subsequent dissociation (ionization) of hypochlorous acid. Draw
breakpoint chlorine dosage curve, and provide explanation to each
zone
During disinfection at large water treatment plants, operators
add chlorine gas to water to make hypochlorous acid (HOCl is weak
acid with pKa = 7.54). In backyard swimming pools, homeowners
accomplish disinfection by adding sodium hypochlorite (NaOCl).
Predict the qualitative change in pH (up or down) due to (a) adding
HOCl to water and (b) adding NaOCl to water. Explain your reasoning
based on LeChatelier’s Principle.
Evidence is fairly strong that chlorine, used for wastewater
disinfection, combines with organic material in wastewater to form
trihalomethane and other disinfection byproducts that are suspected
human carcinogens. Despite this health risk, chlorine remains the
predominant disinfection method. Explain why.
Chlorine gas (Cl2) can be produced by reaction of
hydrochloride acid with manganese oxide. What is the volume of
chlorine gas is produced by adding 1 g of MnO2 to one
litre of 1 M HCl?
MnO2 + 4HCl -> MnCl2 + Cl2 +
2H2O
How much chlorine gas is produced when instead of 1 g
MnO2 this time 50 g MnO2 is added?
What historical events led to the discovery of water-borne
pathogens?
(b) What municipal drinking water disinfection method led to
significant reductions in water-borne pathogenic diseases in
cities?
(c) What is the main disadvantage of the disinfection method
listed in part (b)?
The following mechanism has been proposed for the gas-phase
reaction of chloroform (CHCl3) and chlorine:
1) Cl2 ⇔ 2 Cl (fast, reversible)
2) Cl + CHCl3 → HCl + CCl3 (slow)
3) Cl + CCl3 → CCl4 (fast)
What rate law does this mechanism predict? Choose from the list
below and enter the letters for all the terms needed in the rate
law. (So for a rate law of k[Cl2] enter AC, and for a
rate law of k[Cl2][CHCl3] enter...
Chlorine is produced industailly by the electrolysis of brine.
The reaction is described by the equation
2NaCl (aq) + 2H20 (l) ---------------> 2NaOH (aq) + Cl2 (g) +
H2
(electrolysis)
How many kilograms of each product can be obtained from the
electrolysis of salt that is 95% sodium chloride by mass?
ENVIRONMENTAL ENGINEERING - When Cl2 gas is added to water for
disinfection, it hydrolyzes with water to form HOCl. The combined
concentrations of HOCl and OCl- is called “free chlorine” and the
pKa for HOCl is 7.5. What percentage of the total disinfection
power (measured as CT OCl- ) exists in the acid form at pH = 6? At
pH = 7? Which form is a stronger disinfectant?