Question

In: Chemistry

The solubilities of three salts in water are shown in the graph. A plot has solubility...

The solubilities of three salts in water are shown in the graph. A plot has solubility in grams per liter on the y axis and temperature in degrees Celsius on the x axis. There are three solubility curves, P b (N O 3) 2, K C l, and K 2 C r 2 O 7. Relevant data is summarized. P b (N O 3) 2: 750 grams per liter at 40 degrees Celsius. K C l: 400 grams per liter at 40 degrees Celsius. K 2 C r 2 O 7: 200 grams per liter at 40 degrees Celsius. For each salt, determine how much will remain undissolved if 500 g is mixed into a liter of pure water at 40 ∘C. One significant figure is sufficient in each answer. Pb(NO3)2 : g KCl : g K2Cr2O7 : g

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Expert Solution

Answer : The solubilities of three salts in water are shown in the graph. A plot has solubility in grams per liter on the y axis and temperature in degrees Celsius on the x axis. There are three solubility curves, Pb(NO3)2, KCl, and K2Cr2O7. Relevant data is summarized. Pb(NO3)2 : 750 grams per liter at 40 degrees Celsius. KCl: 400 grams per liter at 40 degrees Celsius. K2Cr2O7 : 200 grams per liter at 40 degrees Celsius.

For each salt i.e. given above, we have determined how much amount will remain undissolved if 500 g is mixed into a liter of pure water at 40 0C. One significant figure is sufficient in each answer. Pb(NO3)2 : g KCl : g and K2Cr2O7 : g

For that now let us see the solubilites of the above given salt i.e. Pb(NO3)2, KCl, and K2Cr2O7 which is given as above

That is, the solubility of the Pb(NO3)2 is 750 grams per liter at 40 degrees Celsius.

Similarly, the solubility of KCl is 400 grams per liter at 40 degrees Celsius

And the solubility of K2Cr2O7 is 200 grams per liter at 40 degrees Celsius

So, if 500 g is mixed into a liter of pure water at 40 0C then amount of the above given salt that would remain undissolved is shown as follows :

(1) The amount of Pb(NO3)2 that would remain undissolved is 0 gram. Since the solubility of the Pb(NO3)2 at 40 degrees Celsius is 750 grams per liter which is more than the 500 gram. So, if 500 g of Pb(NO3)2 is mixed into a liter of pure water at 40 0C then amount of the Pb(NO3)2 salt that would remain undissolved is 0 gram since the solubility of Pb(NO3)2 is more than the amount of salt dissolved in water at 40 degrees Celsius. So, salt will completely dissolve in water at 40 degrees Celsius. And thus, amount of Pb(NO3)2   that would remain undissolved is 0 gram.

(2) The amount of KCl that would remain undissolved is 100 gram. Since the solubility of the KClat 40 degrees Celsius is 400 grams per liter which is less than the 500 gram. So, if 500 g of KCl is mixed into a liter of pure water at 40 0C then amount of the KCl salt that would remain undissolved is 100 gram since the solubility of KCl is les than the amount of salt dissolved in water at 40 degrees Celsius. So, only 400 gram of KCl would dissolve in pure water at 40 degrees Celsius and the amount of salt left would be equal to which is shown as follows :

(Amount of total KCl available - Amount of KCl dissolved at 40 degrees Celsius) i.e.

(500 gram - 400 gram = 100 gram)

since Amount of total KCl available = 500 gram and Amount of KCl dissolved at 40 degrees Celsius = 400 gram (as seen from its solubility at 40 degrees Celsius)

Thus, if 500 g of KCl is mixed into a liter of pure water at 40 0C then amount of the KCl that would remain undissolved is 100 gram.

(3) The amount of K2Cr2O7 that would remain undissolved is 300 gram. Since the solubility of the K2Cr2O7 at 40 degrees Celsius is 200 grams per liter which is less than the 500 gram. So, if 500 g of K2Cr2O7 is mixed into a liter of pure water at 40 0C then amount of the K2Cr2O7 salt that would remain undissolved is 300 gram since the solubility of K2Cr2O7 is les than the amount of salt dissolved in water at 40 degrees Celsius. So, only 200 gram of K2Cr2O7 would dissolve in pure water at 40 degrees Celsius and the amount of salt left would be equal to which is shown as follows :

(Amount of total K2Cr2O7 available - Amount of K2Cr2O7 dissolved at 40 degrees Celsius) i.e.

(500 gram - 200 gram = 300 gram)

since Amount of total K2Cr2O7 available = 500 gram and Amount of K2Cr2O7 dissolved at 40 degrees Celsius = 200 gram (as seen from its solubility at 40 degrees Celsius)

Thus, if 500 g of K2Cr2O7 is mixed into a liter of pure water at 40 0C then amount of the K2Cr2O7 that would remain undissolved is 300 gram.

Thus, finally Pb(NO3)2 : g KCl : g and K2Cr2O7 : g would be equal to which is shown as follows :

Pb(NO3)2 : 0 g KCl : 100 g and K2Cr2O7 : 300 g

Thus, if we express the above given result in kilograms we have

Pb(NO3)2 : 0 kg KCl : 0.1 kg and K2Cr2O7 : 0.3 kg


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