Question

In: Chemistry

1. Write the solubility equilibrium and the solubility product expression for the following sparingly soluble salts....

1. Write the solubility equilibrium and the solubility product expression for the following sparingly soluble salts.

CaCO3

Cu2S

Sb2S3

2. The solubility of silver bromide, AgBr, at 25

Solutions

Expert Solution

a) CaCO3 Ca+2 + CO3-2

      S                    S            S

Ksp = [ Ca+2][CO3-2]

Ksp = S2

b) Cu2S 2Cu+ + S-2

    S               2 S          S

Ksp = [ Cu+]2[S-2]

Ksp = (2S)2(S) = 4S3

c) Sb2S3 2Sb+3 + 3S-2

        S               2S        3S

     Ksp = [Sb+3]2[S-2 ]3

            = [2S]2[3S ]3

               = 108S5

2) for AgBr

   Ksp = S2

Ksp = (8.8.x.10-7)2

       = 77.44 x 10-14


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