Question

In: Chemistry

A) What is the Hrxno in (kJ) for the reaction below, given the relevant table on...

A) What is the Hrxno in (kJ) for the reaction below, given the relevant table on the info sheet. PbO(s) + 2HBr(g) ---> PbBr2(s)+H2O(g).

a) -273

b) -229

c) -265

d) Not enough information provided.

B. What is the Hrxno in (kJ) for 2PbBr2(s) + 2H2O(g) ---> 2PbO(s) +4HBr(g) using the thermochemical equation in part A.

a) 545

b) 530

c) 458

d) 229

Solutions

Expert Solution

PbO(s) + 2HBr(g) ---> PbBr2(s)+H2O(g).

Hrxn = H0f products - H0f reactants

               = -241.818-278.9 -(-218.99+ 2*-36.4)

                = -229KJ/mole

b. -229

B. 2PbBr2(s) + 2H2O(g) ---> 2PbO(s) +4HBr(g)

Hrxn = H0f products - H0f reactants

              = 4*-36.4+ 2*-218.99-(-2*278.9 + 2*-241.818)

               = 458KJ/mole

Or

PbBr2(s) + H2O(g) ---> PbO(s) +2HBr(g)      Hrxn   = 229Kj/mole

2PbBr2(s) + 2H2O(g) ---> 2PbO(s) +4HBr(g)      Hrxn   = 2*229   = 458Kj/mole

c) 458 >>>>answer


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