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In: Chemistry

The system: 2A + B ↔ 2C ; initially started with 1 mole of B and...

The system: 2A + B ↔ 2C ; initially started with 1 mole of B and 1 mol A in a 1L flask. Keq = 6.8 x 10-5    To calculate the equilibrium concentrations a simplifying assumption (approximation) can be made.

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Expert Solution

             2A   +    B ↔ 2C

I          1            1            0

C       -2x         -x          2x

E    1-2x        1-x          2x

    Ka = [C]^2/[A]^2[B]

   6.8*10^-5   = (2x)^2/(1-2x)(1-x)

6.8*10^-5 *(1-2x)(1-x) = 4x^2

     x = 0.0041

[A]   = 1-2x   = 1-2*0.0041   = 0.9918M

[B]   = 1-x     = 1-0.0041       = 0.9959 M

True >>>>answer


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