Question

In: Chemistry

Consider a heat engine that is 40% efficient and operating with a furnace at a temperature...

Consider a heat engine that is 40% efficient and operating with a furnace at a temperature of 727oC with a cooling reservoir at 27oC

•A. If the heat engine withdraws 1MJ/s from the furnace, what is the rate of entropy loss from the furnace?

•B. What would be the rate of entropy gain in the cold reservoir?

•C. What is the total entropy gain of the system?

D. Do A , B, and C again with zero efficiency ?

Please explain your steps

Solutions

Expert Solution

A) First, you must remember the expression for eficiency in a heat engine:



Where Qh is the heat energy taken from the furnace (Qh always is a negative value), Qc is the heat energy delivered to the reservoir. Both values can be calculated with the following equations:

You know the energy withdraw from the furnace, that is Qh= 1 MJ/s and the temperature of the furnace (Th=727 °C=1000 K), so you can calculate the rate of entropy loss from the furnace :


B)Now taking into account the efficiency expression, you can calculate Qc as follows:


Now, you can determine the rate of entropy gain in the cold reservoir as follows:

Tc=27 °C=300 K

C)Therefore, the total entropy gain of the system would be:

D)When  eficiency is zero, you can say that:

Therefore:

Then, if the Furnace and Reservoir temperatures are the same, the entropy changes will be:

And:



Finally, the the total entropy gain of the zero efficiency system would be:


Therefore, we can say that the less efficiency is, the higher entropy gain will be.


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