In: Chemistry
Consider a heat engine that is 40% efficient and operating with a furnace at a temperature of 727oC with a cooling reservoir at 27oC
•A. If the heat engine withdraws 1MJ/s from the furnace, what is the rate of entropy loss from the furnace?
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•B. What would be the rate of entropy gain in the cold reservoir?
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•C. What is the total entropy gain of the system?
D. Do A , B, and C again with zero efficiency ?
Please explain your steps
A) First, you must remember the expression for eficiency in a heat engine:
Where Qh is
the heat energy taken from the furnace (Qh always is a negative value),
Qc is the heat energy
delivered to the reservoir. Both values can be calculated with the
following equations:
You know the energy withdraw from the furnace, that is
Qh= 1 MJ/s and the
temperature of the furnace (Th=727 °C=1000 K), so you
can calculate the rate of entropy loss from the furnace :
B)Now taking into account the efficiency expression, you can
calculate Qc as follows:
Now, you can determine the rate of entropy gain in the cold
reservoir as
follows:
Tc=27 °C=300 K
C)Therefore, the total entropy gain of the system would
be:
D)When eficiency is zero, you can say that:
Therefore:
Then, if the Furnace and Reservoir temperatures are the same,
the entropy changes will be:
And:
Finally, the the total entropy gain of the zero efficiency system
would be:
Therefore, we can say that the less efficiency is, the higher
entropy gain will be.