In: Chemistry
b. Identify the reducing agent in this reaction.
Reaction |
Observations |
A: Pb(NO3)2 + KI |
Powdery appearance, stuck to the walls of the test tube, solution has a yellow color |
B/C: NiCl2 + AgNO3 |
Powdery white, percipate accumalted as pellets at the bottom |
D: H2SO4 + Indicator |
Yellow color when indicator added |
E: NaOH + Indicator |
Dark blue when indicator is added |
F: H2SO4 + NaOH |
Yellow with 10 drops, then after the 23rd drop turned blue |
G: Na2CO3 + H2SO4 |
After 20 drops Na2CO3 dissolved, after two drops of indicator it turns a dark blue after 20 drops of H2SO4 a gas is produced and changes to yellow, adding more sulfuric acid didn’t produce more bubbles |
H: Mg + H2SO4 |
Solid magnesium strip no longer visible |
B |
C |
|
Mass of empty test tube (g) |
12.358g |
7.675g |
Drops of NiCl2 |
30 |
24 |
Drops of AgNO3 |
20 |
32 |
Conductivity of solution (μS/cm) |
21,521 (μS/cm) |
21,005 (μS/cm) |
Mass of precipitate and test tube (g) |
12.415 g |
7.805 g |
For the reaction F,
a) The balanced reaction is
b) H2SO4 is a dibasic acid, it furnishes two H+ ions per molecule in water. We requires twice the amount of NaOH of same concentration to change the colour of the solution (change the solution from acidic to basic).
For the reaction G,
a) The balanced reaction is
The gas released is carbon dioxide.
b) At the end of the reaction, solution is yellow in colour. It indicates that the solution is acidic. The limiting reagent here is Na2CO3 since it is the reactant which is completely used up during the reaction.
c) The product formed is Na2SO4. It is soluble in water and hence exist as Na+ and SO42- ions.
Let n moles of Na+ is present in a solution of molality m and volume v before reaction. Then, the final solution will have the volume 2v (same volume of sulphuric acid is added to nuetralise the base)
molality = n/2v = m/2.
Therefore, molality of Na+ ions reduces to half in the final solution.
For the reaction H,
a) balanced reaction is
Gas released is H2. Here Mg is oxidised and hence it is the reducing agent.