Question

In: Chemistry

If you mix equal concentrations of reactants and products, which of the following reaction proceed to...

If you mix equal concentrations of reactants and products, which of the following reaction proceed to the right and which proceed to the left?

a. H2CO3(aq) + HSO4 (aq) ⇌ H2SO4(aq) + HCO3 (aq)

b. HF(aq) + Cl (aq) ⇌ HCl(aq) + F (aq)

c. HF(aq) + NH3(aq) ⇌ NH4 + (aq) + F (aq)

d. HSO4 (aq) + CN (aq) ⇌ HCN(aq) + SO42−(aq)

e. [Al(H2O)6] 3+(aq) + OH (aq) ⇌ [Al(H2O)6(OH)]2+ (aq) + H2O(l)

Solutions

Expert Solution

The question can be answered on the basis of the relative strengths of acids and bases. It must be noted that a strong acid reacts to form a weak acid. The same thing holds true for bases: a strong base proceeds to form a weak base.

a) H2CO3 (aq) + HSO4- (aq) <=====> HCO3- (aq) + H2SO4 (aq)

H2SO4 is a much stronger acid than H2CO3; hence, the reverse reaction is favored, i.e, the reverse reaction proceeds to form more H2CO3.

b) HF (aq) + Cl- (aq) <======> F- (aq) + HCl (aq)

HCl is a much stronger acid than HF; hence, the reverse reaction is favored and more HF is produced.

c) HF (aq) + NH3 (aq) <=====> F- (aq) + NH4+ (aq)

HF is a stronger acid than NH4+; hence, the reaction proceeds in the forward direction to produce more NH4+.

d) HSO4- (aq) + CN- (aq) <=====> SO42- (aq) + HCN (aq)

HSO4- is a much stronger acid than HCN; hence, the reaction proceeds to the right to give HCN.


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