Question

In: Chemistry

In a reaction bromobenzene is reacting with NO2+ cation to form C6H4NO2Br +C6H3N2O4Br +C6H2N3O6Br Determine the...

In a reaction bromobenzene is reacting with NO2+ cation to form C6H4NO2Br +C6H3N2O4Br +C6H2N3O6Br Determine the m/z values for bromobenzene and its potential mono-, di-, and tri-nitro derivatives.

Solutions

Expert Solution

m/z value is nothing but molar mass value for M+ (Molecular ion) ion for any compound.

Calculate Molar mass of any compound from the summation of all individual atomic massess

For example

bromobenzene (C6H4NO2Br) = [(6 x C) + (4 x H) + (1 x N) + (2 x O) + (1 x Br)]

                                           = [(6 x 12.0107) + (4 x 1.00794) + (1 x 14.0067) + (2 x 15.9994) + (1 x 79.904)]

                                           = 202.0055 g/mol

1. bromobenzene (C6H4NO2Br)    ------      m/z at 202

2. dibromobenzene (C6H3N2O4Br)    ------      m/z at 247

3. tribromobenzene (C6H2N3O6Br)    ------      m/z at 292


Related Solutions

In a particular redox reaction, NO2
In a particular redox reaction, NO2
The reaction:   N2O5 (g)      NO3 (g)   +   NO2 (g) a. Determine the rate order by plotting...
The reaction:   N2O5 (g)      NO3 (g)   +   NO2 (g) a. Determine the rate order by plotting the data. (Hint: Which plot gives a straight line? Conc vs time, ln(conc) vs time, or 1/conc vs time) b. Predict the concentration of N2O5 at 250 seconds. Time (s) [N2O5] 0 1.00 25 0.822 50 0.677 100 0.557 125 0.458 150 0.377
why is it unlikely for magnesium to form a cation with a charge of 1+?
why is it unlikely for magnesium to form a cation with a charge of 1+?
Consider the reaction: 2 NO2 (g) ⇌ N2O4 (g) The ΔGf° for NO2 (g) = 52...
Consider the reaction: 2 NO2 (g) ⇌ N2O4 (g) The ΔGf° for NO2 (g) = 52 kJ/mol and for N2O4 (g) = 98 kJ/mol at 298 K. Calculate the ΔG at the following values. 0.8 M NO2 (g) & 3.0 M N2O4 (g) 4.0 M NO2 (g) & 0.9 M N2O4 (g) 2.2 M NO2 (g) & 2.4 M N2O4 (g) 2.4 M NO2 (g) & 2.2 M N2O4 (g)
In the reaction, H3O+ is the HNO2 + H2O ⇆ H3O+ + NO2-
In the reaction, H3O+ is the HNO2 + H2O ⇆ H3O+  + NO2- A) conjugate base of HNO2. B) conjugate acid of HNO2. C) conjugate acid of H2O. D) conjugate base of H2O.
Bromobenzene -----> triphenyl carbinol via Grignard reaction (a) How could you follow this reaction using spectroscopy,...
Bromobenzene -----> triphenyl carbinol via Grignard reaction (a) How could you follow this reaction using spectroscopy, IR, NMR? Be specific.                   (b) How could you follow this reaction using TLC? Be specific. (6 pts.)
For the reaction, 2 N2O5--> 4 NO2+O2, the rate of formation of NO2 is 0.004 mol^-1...
For the reaction, 2 N2O5--> 4 NO2+O2, the rate of formation of NO2 is 0.004 mol^-1 s^-1. A) Calculate the rate of disappearance of N2O5 B) Calculate the rate of appearance of O2
Why does the nitration of bromobenzene form ortho and para products in an Electrophilic Aromatic Substitution...
Why does the nitration of bromobenzene form ortho and para products in an Electrophilic Aromatic Substitution reaction?
The reaction                                     NO(g) + O3 -> NO2(g) + O2(g
The reaction                                     NO(g) + O3 -> NO2(g) + O2(g) was studied in 2 experiments under pseudo-first order conditions. a) [O3] = 1x1014 molecules/cc in excess the [NO] varied as follows   {Note, time is in msec (1 msec = 1x10-3 s)!}             time (msec)                 NO (molecules/cc)                         0                      6x108                           100                  5x108                           500                  2.4x108                         700                  1.7x108                         1000                9.9x107 b) [NO] = 2x1014 molecules/cc in excess                  time (msec)                 O3 (molecules/cc)                         0                      1x1010                         50                    8.4x109                                   ...
1. In a Quelling reaction test, the antibodies added to the sputum sample are reacting to...
1. In a Quelling reaction test, the antibodies added to the sputum sample are reacting to what morphological feature on the bacterium which causes the bacterium to swell - a positive test result. outer membrane flagellum capsule cell wall 2. When the Western Blot is used to test for Lyme Disease what the procedure is testing for specifically in the individual is the presence of   fragments of the bacterial outer membrane the bacterium specific DNA sequences from the bacterium antibodies...
ADVERTISEMENT
ADVERTISEMENT
ADVERTISEMENT