In: Chemistry
a)
i) wavelength of photon
Energy of photon ,E = hv
where,
v = frequency = c/wavelength
c = speed of light , 2.99×10^8m/s
h = planck constant , 4.136×10^-15 eV.s
therefore,
2.24ev = 4.136 × 10^-15 eV.s × 2.99×10^8(m/s)/wavelength
wavelength = 4.136 × 10^-15 eV.s × 2.99×10^8(m/s)/2.24eV
= 5.5208 ×10^-7m
= 552.08× 10^-9 m
= 552.08nm
ii) wavelength of electron
De Broglie wavelength , = h/mv
where,
h = planck constant , 6.626 × 10^-34 kg m^2 /s
m = mass of electron , 9.11 × 10^-31kg
v = speed of electron
Kinetic energy of electron , E = 1/2 m v^2 = 100000eV=1.602 × 10^-14J = 1.602 × 10^-14 kg ( m^2/s^2)
1.602×10^-14(kgm^2/s^2)= 1/2 × 9.11×10^-31kg × v^2
v^2 = 2 × 1.602 × 10^-14(kg m^2/s^2)/9.11×10^-31kg
v^2 = 3.517 × 10^16 m^2/s^2
v = 1.875 × 10^8m/s
Therefore,
wavelength
= 6.626 ×10^-34 kg m^2/s/9.11×10^-31kg × 1.875×10^8m/s
= 3.879× 10^ -11m
Therefore,
wavelength of electron = 3.879×10^-11m
iii) wavelength of photons is the higher wave lengths