Question

In: Chemistry

A silicon (Φ = 7.77 × 10-19 J) surface is irradiated with UV radiation with a...

A silicon (Φ = 7.77 × 10-19 J) surface is irradiated with UV radiation with a wavelength of 259 nm.
what is the ke of the emitted electrons, what is the speed of the emmited electrons, what is the wavelength of the emmited electrons

Solutions

Expert Solution

A) Work function of Silicon (WO) = hvo

Therefore vo = WO/h = 7.77x10-19J/ 6.626x10-34J.sec

= 1.17x1014/sec

B) λo =c/vo = 3x108 / 1.17x1014 = 3.42x10-7m

C) K.E of ejected electron = h(v-vo) = hc(1/λ – 1/ λo)

=(6.626x10-34J.secx3x108m/sec) (1/259x10-9 – 1/342x10-9)m

=(6.626x3x10-17) (9.4x10-4)J

=18.7x10-20J

We know that KE.=1/2 mv2

k.E = 1mv2/2 = 18.7x10-20J

=9.1x10-31Kg. v2/2 = 18.7x10-20J

Or

v2 = 41.1x1010m2s-2

Or

v = 6.41x105ms-1

Wave length of the emitted electron =hc/KE

                                                         = 6.626x10-34J.sec.x3x108m/sec/(18.7x10-20J)

                                                         = 1.06x10-6m

Hence, the wavelength of the emitted electron is : 1.06x10-6m


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