Question

In: Chemistry

Draw the molecular orbital diagram for the valence electrons in H2O. Using the electron configuration and...

Draw the molecular orbital diagram for the valence electrons in H2O. Using the electron configuration and the Walsh correlation diagram, explain why H2O is bent and not linear.

Solutions

Expert Solution

In the water molecule the highest occupied orbital, (1b1) is non-bonding and highly localized on the oxygen atom, similar to the non-bonding orbitals of hydrogen fluoride. The next lowest orbital (2a1) can be thought of as a non-bonding orbital, as it has a lobe pointing away from the two hydrogens. From the lower energy bonding orbitals, it is possible to see that oxygen also takes more than its "fair share" of the total electron density.

Walsh diagrams, often called angular coordinate diagrams or correlation diagrams, are representations of calculated orbital energies of a molecule versus a distortion coordinate, used for making quick predictions about the geometries of small molecules. By plotting the change in molecular orbital levels of a molecule as a function of geometrical change, Walsh diagrams explain why molecules are more stable in certain spatial configurations.


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