In: Chemistry
_____1. | 0.15 m | Na2S | A. | Highest boiling point | ||
_____2. | 0.11 m | Cr2(SO4)3 | B. | Second highest boiling point | ||
_____3. | 0.17 m | MnCl2 | C. | Third highest boiling point | ||
_____4. | 0.47 m | Glucose(nonelectrolyte) | D. | Lowest boiling point |
The boiling points of the following will be as follows,
We will consider the relation,
The equation for BP elevation is:
delta Tb = Kb x i x m
delta Tb the boiling point elevation
Kb is the ebullioscopic constant (will remain constant for all)
i = no of ions in solution
m = molality of solution
thus,
calculating for all we get,
1) 0.15 m Na2S has 3 ions
Thus,
delta Tb = 3 x 0.15 = 0.45
2) 0.11 m Cr2(SO4)3 has i = 5
Thus,
delta Tb = 5 x 0.11 = 0.55
3) 0.17 m MnCl2 has i = 3
thus,
delta Tb = 3 x 0.17 = 0.51
4) 0.47 m Glucose (non-electrolyte) has i = 1
Thus,
delta Tb = 1 x 0.47 = 0.47
From all the above calculation we can clearly say that (according to the boiling point elevation values),
1. 0.15 m Na2S will have : D lowest boiling point
2. 0.11 m Cr2(SO4)3 will have : A Highest boiling point
3. 0.17 m MnCl2 will have : B Second highest boiling point
4. 0.47 m Glucose will have : C third highest boiling point