In: Chemistry
In Zinc blende structure______
(a) zinc ions occupy half of the tetrahedral sites
(b) each Zn2- ion is surrounded by six sulphide ions
(c) each S2- ion is surrounded by six Zn2+ ions
(d) it has free site
Explanation :
Zinc sulfide (ZnS) is an unique compound which forms two types of crystalline structures. These two polymorphs are wurtzite and zincblende (also known as sphalerite). Wurtzite has a hexagonal structure, while zincblende is cubic.
The Zn2+ ions are present in the alternative tetrahedral void. Each Zn2+ ion is surrounded tetrahedrally by four S2- ions and each S2- ion is surrounded tetrahedrally by four Zn2+ ions. Thus the structure has 4:4 coordination.
(a) zinc ions occupy half of the tetrahedral sites.