Question

In: Chemistry

A 100.0 mL sample of 0.10 M NH3 is titrated with 0.10 M HNO3. Determine the...

A 100.0 mL sample of 0.10 M NH3 is titrated with 0.10 M HNO3. Determine the pH of the solution after the addition of 50.0 mL of HNO3. The Kb of NH3 is 1.8 × 10-5.

Solutions

Expert Solution

no of moles of NH3 = molarity * volume in L

                                  = 0.1*0.1 = 0.01 moles

no of moles of HNO3 = molarity * volume in L

                                    = 0.1*0.05 = 0.005 moles

                 NH3 + HNO3 ---------------> NH4NO3

I              0.01       0.005                         0

C          -0.005    -0.005                          0.005

E           0.005        0                              0.005

                   Kb = 1.8*10^-5

                    PKb = -logKb   = -log1.8*10^-5 = 4.75

             POH   = PKb + log[NH4NO3]/[NH3]

                       = 4.75 + log0.005/0.005

                      = 4.75 +0

                       = 4.75

          PH    = 14-POH

                    = 14-4.75 = 9.25


Related Solutions

A 100.0 mL sample of 0.10 M NH3 is titrated with 0.10 M HNO3. Determine the...
A 100.0 mL sample of 0.10 M NH3 is titrated with 0.10 M HNO3. Determine the pH of the solution after the addition of 50.0 mL of HNO3. The Kb of NH3 is 1.8 × 10-5.
1. A 100.0 mL sample of 0.10 M NH3 is titrated with 0.10 M HNO3. Kb,...
1. A 100.0 mL sample of 0.10 M NH3 is titrated with 0.10 M HNO3. Kb, NH3 = 1.8 × 10−5. Determine the pH of the solution at each of the following points in the titration: (a) before addition of any HNO3 (b) after the addition of 50.0 mL HNO3 (c) after the addition of 75.0 mL HNO3 (d) at the equivalence point (e) after the addition of 150.0 mL HNO3 2. (12 points) Consider the titration of 37.0 mL...
Q4, A 100.0mL sample of 0.10 M NH3 is titrated with 0.10 M HNO3 Determine the...
Q4, A 100.0mL sample of 0.10 M NH3 is titrated with 0.10 M HNO3 Determine the pH of the solution after addition of 100ml of HNO3 The kb of NH3 is 1.8x10-5
A 100.0 mL sample of 0.20 M HF is titrated with 0.10 M KOH. Determine the...
A 100.0 mL sample of 0.20 M HF is titrated with 0.10 M KOH. Determine the pH of the solution after the addition of 200.0 mL of KOH. The Ka of HF is 3.5 × 10-4. Answer: 8.14 but how do I get this?? I'm so lost!
A 100.0 mL sample of 0.20 M HF is titrated with 0.20 M KOH. Determine the...
A 100.0 mL sample of 0.20 M HF is titrated with 0.20 M KOH. Determine the pH of the solution after the addition of 50.0 mL of KOH. The Ka of HF is 3.5 × 10-4. A. 2.08 B. 3.15 C. 4.33 D. 3.46 E. 4.15
Consider the following four titrations. i. 100.0 mL of 0.10 M HCl titrated by 0.10 M...
Consider the following four titrations. i. 100.0 mL of 0.10 M HCl titrated by 0.10 M NaOH ii. 100.0 mL of 0.10 M NaOH titrated by 0.10 M HCl iii. 100.0 mL of 0.10 M CH3NH2 titrated by 0.10 M HCl iv. 100.0 mL of 0.10 M HF titrated by 0.10 M NaOH Rank the titrations in order of: increasing volume of titrant added to reach the equiva- lence point. increasing pH initially before any titrant has been added. increasing...
5) A 100.0 mL sample of 0.18 M HClO4 is titrated with 0.27 M LiOH. Determine...
5) A 100.0 mL sample of 0.18 M HClO4 is titrated with 0.27 M LiOH. Determine the pH of the solution a) before the addition of any LiOH. b) after the addition of 30.0 mL of LiOH. c) after the addition of 50.0 mL of LiOH. d) after the addition of 66.67 mL of LiOH (this is the equivalence point). e) after the addition of 75.0 mL of LiOH.
A 35.0 mL sample of 0.150 M ammonia (NH3, Kb=1.8×10−5) is titrated with 0.150 M HNO3....
A 35.0 mL sample of 0.150 M ammonia (NH3, Kb=1.8×10−5) is titrated with 0.150 M HNO3. Calculate the pH after the addition of each of the following volumes of acid. Express your answer using two decimal places. A. 0.0 mL B. 17.5 mL C. 35.0 mL D. 80.0 mL
A 100.0 mL sample of 0.100 M methylamine (CH3NH2;Kb=3.7×10−4) is titrated with 0.250 M HNO3. Calculate...
A 100.0 mL sample of 0.100 M methylamine (CH3NH2;Kb=3.7×10−4) is titrated with 0.250 M HNO3. Calculate the pH after the addition of each of the following volumes of acid. Part A: 0.0 mL Part B: 20.0 mL Part C: 40.0 mL Part D: 60.0 mL
A student reacted 100.0 mL of 0.9800 M HCl with 100.0 mL of 0.9900 M NH3....
A student reacted 100.0 mL of 0.9800 M HCl with 100.0 mL of 0.9900 M NH3. The density of                           the reaction mixture was 1.02 g/mL and the heat capacity was 4.016 J/g K.                           Calculate the enthalpy of neutralization by plotting and using the data shown below. Time(min) Temp(oC) 0.0 23.25 0.5 23.27 1.0 23.28 1.5 23.30 2.0 23.30 3.0 23.35 4.0 23.44 4.5 23.47 mix --------- 5.5 28.75...
ADVERTISEMENT
ADVERTISEMENT
ADVERTISEMENT