Why is it not possible to assign R or S to a compound if it is...
Why is it not possible to assign R or S to a compound if it is
drawn such that the lowest-priority substituent is in the plane of
the paper? What are some ways to handle this situation?
Solutions
Expert Solution
In the CIP system of nomenclature, each chiral center in a
molecule is assigned a prefix (R or S), according to whether its
configuration is right- or left-handed. The symbol R comes from the
Latin rectus for right, and S from the Latin sinister for left. The
assignment of these prefixes depends on the application of two
rules: The Sequence Rule and The Viewing Rule. The
viewing rule states that when the lowest priority substituent is
oriented behind the triangular face defined by the three higher
priority substituents, a clockwise sequential arrangement of these
substituents is defined as R, and a counter-clockwise
sequence as S.
If the lowest priority group is in the plane of the paper, it will
be difficult to assign the priorities of the groups attached to the
tetrahedral carbon in either clockwise or anticlockwise
manner.
Now a tetrahedral structure may be viewed from any of the four
triangular faces, and the symmetry of the system is such that a
correct R/S assignment is made if the remote out-of plane group has
an even number sequence priority (2 or 4), whereas the wrong
assignment results when the out-of plane group has an odd priority
(1 or 3). Once one recognizes this relationship, the viewing
options are increased and a configurational assignment is more
easily achieved.
A
compound gear train with gears P, Q, R, S, T and U has number of
teeth 10, 20, 02 40, 50, 80 and 100 respectively. Show the
arrangement of gears for a speed reduction of 50% and determine the
center distance between driving and driven shafts if the
diametrical pitch of the gears is 0.5
I
only have this question , cant give you more information
As far as possible, assign the following terms to the
definitions and descriptions below. To do this, enter the
corresponding letter in the table to the left of the term. If no
definition matches the term, please enter "-".
Definitions and descriptions:
A. Term for a quantity expressed in terms of a point in
time (e.g. capital stock).
B. Increases net welfare in the presence of negative external
effects.
C. Selling price minus costs of a
good.
D. ...
a) Let S ⊂ R, assuming that f : S → R is a continuous function,
if the
image set {f(x); x ∈ S} is unbounded prove that S is unbounded.
b) Let f : [0, 100] → R be a continuous function such that f(0) =
f(2),
f(98) = f(100) and the function g(x) := f(x+ 1)−f(x) is equal to
zero in at most
two points of the interval [0, 100].
Prove that (f(50) − f(49))(f(25) − f(24)) >...
Let R and S be rings. Denote the operations in R as
+R and ·R and the operations in S as
+S and ·S
(i) Prove that the cartesian product R × S is a ring, under
componentwise addition and multiplication.
(ii) Prove that R × S is a ring with identity if and only if R
and S are both rings with identity.
(iii) Prove that R × S is a commutative ring if and only if R
and...
could you please assign this homework to this person
if possible: Dumpydnp
Write a 200- to 400-word essay about the most
important thing you learned while watching "Freedom of
Speech."" Please answer based on the
video-thank you
Please watch the video- do not copy and paste from
internet-thank you
link:
https://www.youtube.com/watch?v=Zeeq0qaEaLw&list=PL8dPuuaLjXtOfse2ncvffeelTrqvhrz8H&index=25
or typing in youtube: Freedom of Speech: Crash Course Government
and Politics #25
could you please assign this homework to this person
if possible: Dumpydnp
Write a 200- to 400-word essay about the most important thing
you learned while watching "Freedom of the Press." please
answer based on the video- short video
do not copy and paste from internet -thank
you
watch this video by typing in youtube: Freedom of the Press:
Crash Course Government and Politics #26
or link
:https://www.youtube.com/watch?v=Vtpd0EbaFoQ&list=PL8dPuuaLjXtOfse2ncvffeelTrqvhrz8H&index=26