Question

In: Chemistry

Grasshopper ketone is a natural product isolated from the flightless grasshopper Romalea microptera. From its structure,...

Grasshopper ketone is a natural product isolated from the flightless grasshopper Romalea microptera. From its structure, locate the next types of bonds or atoms. (Note: the dark dot in the middle of the double bonds corresponds to the presence of a carbon.)

An sp3-hybridized carbon atom

A highly polarized covalent single bond

A nearly nonpolar covalent bond

An sp2-hybridized carbon atom

A highly polarized covalent double bond

An sp-hybridized carbon atom

A bond between atoms of different hybridizations

Solutions

Expert Solution

Identification of carbons and structure

An sp3-hybridized carbon atom : CH3 or CH2 or CH or C (quaternary carbon)

A highly polarized covalent single bond : C-heteroatom (heteroatom could be O)

A nearly nonpolar covalent bond : CH3-CH2 as in sp3-sp3 linkage

An sp2-hybridized carbon atom : C= [carbon with a doble bond]

A highly polarized covalent double bond : C=O linkage

An sp-hybridized carbon atom : Carbon with a triple bond or carbon with two double bonds

A bond between atoms of different hybridizations : =C-CH3, is a bond between sp2 C and sp3 carbon


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