Question

In: Chemistry

The acid ionization constant for Ga(H2O)63+ (aq) is 2.5×10-3 . Calculate the pH of a 0.1500...

The acid ionization constant for Ga(H2O)63+ (aq) is 2.5×10-3 . Calculate the pH of a 0.1500 M solution of Ga(NO3)3 .

Solutions

Expert Solution

Ka for Ga(H2O)63+ (aq) = 2.5×10^-3 .

Ga(H2O)63+ (aq)   --------------->   Ga(H2O)5.(OH)2+ + H+

0.1500                                                      0                       0

0.1500 - x                                                  x                       x

Ka = x^2 / 0.15 - x

2.5 x 10^-3 = x^2 / 0.15 - x

x = 0.0182

[H+] = 0.0182 M

pH = -log (0.0182)

pH = 1.74


Related Solutions

The acid ionization constant for Co(H2O)62+(aq) is 3.0×10-10. Calculate the pH of a 0.0229 M solution...
The acid ionization constant for Co(H2O)62+(aq) is 3.0×10-10. Calculate the pH of a 0.0229 M solution of Co(NO3)2.
The acid ionization constant for Pb(H2O)62+(aq) is 6.3×10-7. Calculate the pH of a 0.0442 M solution...
The acid ionization constant for Pb(H2O)62+(aq) is 6.3×10-7. Calculate the pH of a 0.0442 M solution of Pb(NO3)2. pH =
The acid ionization constant for Fe(H2O)62+(aq) is 3.0×10-6. Calculate the pH of a 0.0394 M solution...
The acid ionization constant for Fe(H2O)62+(aq) is 3.0×10-6. Calculate the pH of a 0.0394 M solution of Fe(NO3)2.
Calculate the ionization constant of acetic acid: pH of 0.01 M acetic acid: 3.50 pH of...
Calculate the ionization constant of acetic acid: pH of 0.01 M acetic acid: 3.50 pH of 1.00 M acetic acid: 2.34
Cacodylic acid is (CH3)2AsO2H. Its ionization constant is 6.4 × 10−7. (a) Calculate the pH of...
Cacodylic acid is (CH3)2AsO2H. Its ionization constant is 6.4 × 10−7. (a) Calculate the pH of 50.0 mL of a 0.18 M solution of the acid. (b) Calculate the pH of 25.0 mL of 0.15 M (CH3)2AsO2Na. (c) Mix the solutions in parts (a) and (b). Calculate the pH of the resulting solution..
Phosphoric acid, H3PO4(aq), is a triprotic acid. Calculate the pH and concentrations of H3O + (aq),...
Phosphoric acid, H3PO4(aq), is a triprotic acid. Calculate the pH and concentrations of H3O + (aq), H3PO4(aq), H2PO4 − (aq), HPO4 2− (aq), PO4 3− (aq), and OH− (aq) in a 0.100-M phosphoric acid solution at 25°C.
Calculate the pH of a 0.19 M CH3NH3+ solution. CH3NH2+(aq) + H2O(l) = CH3NH3+(aq) + OH-(aq)...
Calculate the pH of a 0.19 M CH3NH3+ solution. CH3NH2+(aq) + H2O(l) = CH3NH3+(aq) + OH-(aq) Species, Data CH3NH2, Kb = 3.70x10-4. CH3NH2+, Ka = 2.73x10-11.
From the ionization constant, calculate the standard Gibbs free-energy change for the ionization of acetic acid...
From the ionization constant, calculate the standard Gibbs free-energy change for the ionization of acetic acid in water at 25∘C. ΔrG∘ = ??? What is the Gibbs free-energy change at equilibrium for the ionization of acetic acid in water at 25∘C?? What is the Gibbs free-energy change for the following reaction in water at 25∘C ? (Assume that activity coefficients are all equal to 1.) H+ (10−4M) +OAc− (10−2M) →HOAc (1M) ???????????/ What is the Gibbs free-energy change for the...
Consider the ionization of aqueous ammonia: NH3(aq) + H2O(l) ⇌ NH4 + (aq) + OH- (aq)...
Consider the ionization of aqueous ammonia: NH3(aq) + H2O(l) ⇌ NH4 + (aq) + OH- (aq) a)Using the thermodynamic data from the textbook (Appendix C), calculate the values of ∆H°rxn, ∆G°rxn, and ∆S°rxn for this process at 25o C. b)Calculate the value of Kb (with 2 sig figs) at 25o C from the value of ∆G°rxn. c) The value of ∆G°rxn you obtain (if your calculations are correct) must be positive, indicating that the reaction in question is non-spontaneous. Why...
1. 3. Consider the dissociation of acetic acid: CH3COOH(aq) + H2O(l) ⎯→ ←⎯ CH3COO-(aq) + H3O+(aq)...
1. 3. Consider the dissociation of acetic acid: CH3COOH(aq) + H2O(l) ⎯→ ←⎯ CH3COO-(aq) + H3O+(aq) Ka = 1.8 x 10-5    pKa = 4.74 a. Write the equilibrium expression. b. Would the addition of an aqueous solution of sodium hydroxide favor the dissociation of acetic acid? Explain your answer. c. Would the addition of an aqueous solution of sodium acetate favor the dissociation of acetic acid? Explain your answer.
ADVERTISEMENT
ADVERTISEMENT
ADVERTISEMENT