Question

In: Chemistry

What does it mean for a free energy diagram of an equilibrium reaction when delta G...

What does it mean for a free energy diagram of an equilibrium reaction when delta G is zero? Does that mean that the entire diagram would just be a horizontal line, or would there still be transition and intermediate states?

Solutions

Expert Solution

It is a very nice question first of all...now lets discuss this,

The answer lies in the definition of equilibrium...which is..at equilibrium RATE of formation of products is EQUAL to RATE of formation of reactant.
Now this means reaction has not stopped.. it just seems like stop..but bond from product side is breaking to form reactant and same thing is happening from reactant side...which obviously require energy otherwise it will be violation of "law of conservation of energy" which says energy can neither be created nor be destroyed...so this proves that the diagram is definitely not a straight line but a small plateau...which can easily be crossed by both the sides(reactant and product)...
Now if there is a plateau so there is definitely a trasition state which involves the breaking and forming of bonds (which obviously cant be isolated)..but not intermediate state because that will change the profile of reaction coordinate of equilibrium.

Hope you got the answer please give feedback


Related Solutions

What is an option delta? If delta is 0.5 what does this mean? How does delta...
What is an option delta? If delta is 0.5 what does this mean? How does delta change when the option is in-the-money, at-the-money, and out-of-the-money
Calculate the free energy of transport (Delta G) for the movement of sodium ions (Na+ )...
Calculate the free energy of transport (Delta G) for the movement of sodium ions (Na+ ) from the extracellular space into the cell under the following conditions: [Na+ ]out = 140 mM; [Na+ ]in = 12.0 mM; membrane potential =−60.0 mV; T = 37.0C. Use R = 8.314 J/mol K; F = 96,500 J/V mol. 2. Calculate the free energy of transport (Delta G) for the movement of potassium ions (K+ ) from the extracellular space into the cell under...
From Gibbs free energy , if our delta G is found to be negative the process...
From Gibbs free energy , if our delta G is found to be negative the process is said to be spontaneous in the forward manner; so it’s a one way streak because the reverse process is said to be non spontaneous, and to be non spontaneous,( the process won’t occur on it s own with out outside intervention). Question- a negative delta G refers to reaction that will occur on its own with out any outside intervention, and thus it...
Why does an exergonic reaction mean that the products have lower free energy than the reactants,...
Why does an exergonic reaction mean that the products have lower free energy than the reactants, rather than the other way around, where the reactants have lower free energy than the products? Because doesn't an exergonic reaction mean that deltaG is negative?
What does it mean if delta G naught is higher at low temperature (5 degrees celsius)...
What does it mean if delta G naught is higher at low temperature (5 degrees celsius) and lower at high temperature( 25 degree celsius or room temp) but delta S naught is the same at both temperatures? Ksp was also lower at low temp and higher at high temp. Details: Is this as it should be and if so please explain why. All values are positive. Delta G naught= 19.19 kJ/mol at room temp and 23.66 kJ/mol at 5 degrees....
What is the standard free energy change for the reaction below? Is the reaction expected to...
What is the standard free energy change for the reaction below? Is the reaction expected to be spontaneous under standard conditions? FeS(s) + O2(g) → Fe(s) + SO2(g)
What does it mean to diagram an argument?
What does it mean to diagram an argument?
what is a mixed strategy nash equilibrium and what does it mean when a player has...
what is a mixed strategy nash equilibrium and what does it mean when a player has a dominated strategy
Consider the reaction NH4Cl(aq)NH3(g) + HCl(aq) The standard free energy change for this reaction is 62.8...
Consider the reaction NH4Cl(aq)NH3(g) + HCl(aq) The standard free energy change for this reaction is 62.8 kJ. The free energy change when 1.72 moles of NH4Cl(aq) react at standard condition is____ kJ. What is the maximum amount of useful work that the reaction of 1.72 moles of NH4Cl(aq) is capable of producing in the surroundings under standard conditions?_______ If no work can be done, enter none. kJ
K CONSTANT EQUILIBRIUM What does it mean when K=1 and when K= 0
K CONSTANT EQUILIBRIUM What does it mean when K=1 and when K= 0
ADVERTISEMENT
ADVERTISEMENT
ADVERTISEMENT