The atmosphere slowly oxidizes hydrocarbons in a number of steps
that eventually convert the hydrocarbon into carbon dioxide and
water. The overall reactions of a number of such steps for methane
gas is as follows:
CH4(g)+5O2(g)+5NO(g)→CO2(g)+H2O(g)+5NO2(g)+2OH(g)
Suppose that an atmospheric chemist combines 165 mL of methane at
STP, 865 mL of oxygen at STP, and 57.5 mL of NO at STP in a 2.2 −L
flask. The reaction is allowed to stand for several weeks at 275
K.
A) If the reaction reaches 90.0% of completion (90.0% of the limiting reactant is consumed), what are the partial pressures of each of the reactants in the flask at 275 K? (answer as follows: PCH4,PO2,PNO)
B) If the reaction reaches 90.0% of completion (90.0% of the limiting reactant is consumed), what are the partial pressures of each of the products in the flask at 275 K? (answer as follows PCO2,PH2O,PNO2,POH)
C) What is the total pressure in the flask?
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Sodium nitroprusside is ordered at 0.3 mcg/kg/min for a 220-lb patient. A vial containing 50 mg of sodium nitroprusside in 2 mL is diluted to 250 mL with NSI and ordered to run at 14 mL/h. Is this run rate correct? If not, what should be the correct infusion rate? The correct answer is no, and 9 mL/h. Please show how this problem is solved.
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Though they are not necessary in every situation, solvents are used when performing reactions for many reasons. What function does a solvent serve in a reaction (list two)? What characteristics are important to consider when selecting a solvent (list two)? This is regards to organic chemistry, please explain your answers, please!
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What are the factors influencing the transport and behaviour of wastes in the environment?
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Enthalpy H is a measure of the energy content of a system at constant pressure. Chemical reactions involve changes in enthalpy, ΔH, which can be measured and calculated: ΔHrxn∘=∑productsmΔHf∘−∑reactantsnΔHf∘ where the subscript "rxn" is for "enthalpy of reaction" and "f" is for "enthalpy of formation" and m and n represent the appropriate stoichiometric coefficients for each substance. The following table lists some enthalpy of formation values for selected substances. Substance ΔHf∘ (kJ/mol) NaOH(aq) −469.1 MgCl2(s) −641.8 NaCl(aq) −407.3 Mg(OH)2(s) −924.5 H2O(l) −285.8 Part A Determine the enthalpy for this reaction: MgCl2(s)+2NaOH(aq)→Mg(OH)2(s)+2NaCl(aq) Express your answer in kilojoules per mole to one decimal place. ΔHrxn∘ = kJ/mol SubmitMy AnswersGive Up Part B Consider the reaction Mg(OH)2(s)→MgO(s)+H2O(l) with enthalpy of reaction ΔHrxn∘=37.5kJ/mol What is the enthalpy of formation of MgO(s)? Express your answer in kilojoules per mole to one decimal place. ΔHf∘ = kJ/mol Submit
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Use the following information to answer questions 5-10. A student determined the heat of neutralization of copper (II) sulfate (CuSO4) mixed with potassium hydroxide (KOH) using the procedure described part 2 of this experiment. A 150.0 mL sample of a 1.50 M solution of CuSO4 was mixed with a 150.0 mL sample of 3.00 M KOH in a coffee cup calorimeter. The temperature of both solutions and the calorimeter was 25.2 °C before mixing and 31.3 °C after mixing. The heat capacity of the calorimeter is 24.2 J/K. Calculate the heat of reaction (ΔHrxn) for this reaction in units of J/mole of copper (II) hydroxide (Cu(OH)2). Assume the solution is dilute enough that the specific heat capacity and density of the solution is the same as that of water, 4.18 J/g∙K and 1.00 g/mL respectively. Calculate the number of moles of copper (II) hydroxide (Cu(OH)2) formed during this reaction. Assume the reaction goes to 100% completion.
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|
Match the following |
||
|
1 |
[Ar]4s1 |
A. Anion |
|
2 |
a probability map for electrons |
B. Frequency |
|
3 |
[Kr]5s24d105p2 |
C. Electrons |
|
4 |
[Kr] 5s24d105p6 |
D. Photon |
|
5 |
Number of unpaired electrons in Sc |
E. Ground State |
|
6 |
Metals form these when they lose an electron |
F. Excited state |
|
7 |
Electrons in the highest main energy level |
G. Quantized energy |
|
8 |
A sphere-shaped orbital |
H. S orbital |
|
9 |
Number of unpaired electrons in phosphorus |
I. Orbital |
|
10 |
Tiny packets of light |
J. Electron configuration for Tin |
|
11 |
Particle responsible for the |
|
In: Chemistry
Use data in Appendix C in the textbook to calculate ΔH∘ in (kJ/mol) , ΔS∘ in (j/mol-K) , and ΔG∘ in (kJ/mol) at 25 ∘C for each of the following reactions: 2P(g)+10HF(g)→2PF5(g)+5H2(g)
Appendix C:
P(g): dH:316.4; dG: 280.0; S:163.2
HF(g): dH: -268.61; dG: -270.70; S:173.51
PF5(g): dH:-1594.4; dG: -1520.7; S: 300.8
H2(g): dH:217.94; dG: 203.26; S: 114.60
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Which of the following ions or atoms possess paramagnetic properties ?
S
Ar-
S2-
Ar
Na+
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Using (Kf=1.2×109) calculate the concentration of Ni2+(aq), assuming that it is present as Ni(NH3)2+6, at equilibrium after dissolving 1.28 gNiCl2 in 100.0 mL of 0.20 MNH3(aq).
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Compare and contrast the intravascular and extravascular routes of hemoglobin degradation (identify at least two similarities and at least 3 differences)
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What difference between NMR and FTIR in chemical structure characterization?
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