For the reaction below, Kp = 29.95 at 800 K. Calculate the equilibrium partial pressures of the reactants and products if the initial pressures are P_PCl5 = 0.3900 atm and P_PCl3 = 0.4300 atm. Assume Cl2 is 0 atm. PCL5 (g) > PCl3 (g) + Cl2 (g)

#1. Calculate the pH for each of the following cases in the titration of 50.0 mL of 0.200 M HClO(aq) with 0.200 M KOH(aq). The ionization constant of HClO is Ka = 4.0×10^–8.

(a) Before addition of any KOH

(b) After addition of 25.0 mL of KOH

(c) After addition of 30.0 mL of KOH

(d) After addition of 50.0 mL of KOH

(e) After addition of 60.0 mL of KOH

#2 Calculate the pH for each of the following cases in the titration of 25.0 mL of 0.200 M pyridine, C5H5N(aq) with 0.200 M HBr(aq). The ionization constant for pyridine is Kb = 1.7×10^–9.

(a) Before addition of any HBr

(b) After addition of 12.5 mL of HBr

(c) After addition of 20.0 mL of HBr

(d) After addition of 25.0 mL of HBr

(e) After addition of 29.0 mL of HBr

Calculate the pH of each of the solutions and the change in pH to 0.01 pH units caused by adding 10.0 mL of 2.67-M HCl to 540. mL of each of the following solutions. Change is defined as final minus initial, so if the pH drops upon mixing the change is negative. a) water pH before mixing = Correct: Your answer is correct. pH after mixing= pH change = b) 0.153 M C2H3O21- pH before mixing = pH after mixing= pH change = c) 0.153 M HC2H3O2 pH before mixing = pH after mixing= pH change = d) a buffer solution that is 0.153 M in each C2H3O21- and HC2H3O2 pH before mixing = pH after mixing= pH change =

List and describe three pieces of data that support the fact that octahedral complexes undergo dissociative substitution.

Use the accepted nomenclature to write the name of this compound.

[Ag(o-phen)₂]NO₃

notice that "SO4" appears in two different places in the chemical equation SO-2>4 is a poyatomic ion called sulfate. what number should be placed in front of CaSO4 to give the same total number of sulfate ion in each side of the equation?

Three gases (8.00 g of methane, CH4, 18.0 g of ethane, C2H6, and an unknown amount of propane, C3H8) were added to the same 10.0-L container. At 23.0 ∘C, the total pressure in the container is 3.60 atm . Calculate the partial pressure of propane in the container.

Q.3. What kind of post-translational modifications are taking place on collagen? (there are many. So please check the literature carefully). Why are they important for its structure? In terms of post translational processing of collagen, explain why chicken soup that is liquid when cooked fresh, becomes a gel like material upon refrigeration overnight.

Calculate the average thickness of copper on the surface of a penny (produced after 1983) in units of a.) mm and b.) atoms of Cu. Show all calculations, including unit analysis.

A scientist tries to generate a mixture of gases similar to a volcano by introducing 30.0 g of H20 vapor, 7.5 g of SO2, and 2.0 g of CO2 into a 30.0 L vessel held at 110.0˚C. (a)Calculate the total pressure of the CO2 in the mixture if the gasses don’t react. However, water and CO2 react to make liquid carbonic acid H2CO3. Write the balanced chemical reaction. Assuming the reaction is complete, how much carbonic acid is formed and how much of each molecule is in the gas phase. Finally, what is the pressure of the mixture if H2CO3 is not in the vapor phase?

The change in enthalpy for a reaction is -25.8kJ. The equilibrium constant for the reaction is 1400 at 25 degrees Celsius. What is the equilibrium constant at 382 degrees Celsius?

The dibasic compound B (pKb1 = 4.00, pKb2 = 8.00) was titrated with 1.00 M HCl. The initial solution of B was 0.100 M and had a volume of 100.0 mL. Find the pH at the following volumes of acid added and make a graph of pH versus Va; Va=0, 1, 5, 9, 10, 11, 15, 19, 20, and 22mL.

What distance does electromagnetic radiation travel in 10.2 fs ? Express your answer using three significant figures.

Part A

What is the frequency of radiation that has a wavelength of 11 μm , about the size of a bacterium?

Express your answer using two significant figures.

What is the wavelength of radiation that has a frequency of 5.40×10¹⁴ s−1 ?

Would the radiations in part (a) or part (b) be visible to the human eye?

The radiation in (a) is "visible" to humans. The radiation in (b) is "visible" to humans

.What distance does electromagnetic radiation travel in 50.0 μs ?