Question

In: Chemistry

Use the Ksp value in the table to calculate the molar solubility of AgBr, Fe(OH)2, and...

Use the Ksp value in the table to calculate the molar solubility of AgBr, Fe(OH)2, and PbBr2 in pure water

Solutions

Expert Solution

Molar solubility

Ksp

AgBr = 5.0 E-13

Fe(OH)2 = 2.5E-15

Pb(Br)2= 4.6E-6

AgBr (s) -- > Ag+ (aq) + Br- (aq)

I                                     0                    0

C     -x (molar sol.)      +x                  +x

E                                    x                  x

Ksp = [Ag+][Br-]

5.0E-13 = x2

x = 7.07 E-7 M

Molar solubility of AgBr = 7.07E-7 M

Fe(OH)2

            Fe(OH)2(s) --- > Fe2+ (aq) + 2 OH- (aq)

I                                               0                      0

C         -x                                 +x                    +2x

E                                              x                      2x

2.5 E-15 = x (2x)2

2.5E-15 = 4x3

x = 8.55 E-6 M

PbBr2

            PbBr2 (s)     ----- > Pb2+(aq) + 2 Br- (aq)

I                                               0                      0

C                                             +x                    +2x

E                                              x                      2x

4.6 E-6 = 4x3

x = 1.05 E-2 M


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