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Problem 5.1 Consider the formation of glucose from carbon dioxide and water (i.e., the reaction of...

Problem 5.1

Consider the formation of glucose from carbon dioxide and water (i.e., the reaction of the photosynthetic process): 6CO2(g)+6H2O(l)?C6H12O6(s)+6O2(g).
The following table of information will be useful in working this problem:

T= 298 K CO2(g) H2O(l) C6H12O6(s) O2(g)
?H?f (kJ mol?1) -393.5 -285.8 -1273.1 0.0
S? (J mol?1 K?1) 213.8 70.0 209.2 205.2
C?P,m (J mol?1 K?1) 37.1 75.3 219.2 29.4

Part A

Calculate the entropy change for this chemical system at 313 K .

Express your answer to four significant figures and include the appropriate units.

Part B

Calculate the enthalpy change for this chemical system at 313 K .

Express your answer to four significant figures and include the appropriate units.

Part C

Calculate the entropy change of the surroundings at 313 K .

Express your answer to three significant figures and include the appropriate units.

Part D

Calculate the entropy change of the universe at 313 K .

Express your answer to three significant figures and include the appropriate units.

Solutions

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