Question

In: Chemistry

Physical chemistry Could you please search in this topic and use two references and send me...

Physical chemistry
Could you please search in this topic and use two references and send me them with the information that I need.
My topic is Morse Potential
I need a historical background of the equation , who discovered it ,how and when it discovered and why?
Please do not write it in handwriting because sometime does not clear.

Solutions

Expert Solution

From wikipedia ,

The Morse potential, named after physicist Philip M. Morse, is a convenient interatomic interaction model for the potential energy of a diatomic molecule.

It is a better approximation for the vibrational structure of the molecule than the QHO (quantum harmonic oscillator) because it explicitly includes the effects of bond breaking, such as the existence of unbound states. It also accounts for the anharmonicity of real bonds and the non-zero transition probability for overtone and combination bands.

The Morse potential can also be used to model other interactions such as the interaction between an atom and a surface. Due to its simplicity (only three fitting parameters), it is not used in modern spectroscopy. However, its mathematical form inspired the MLR (Morse/Long-range) potential, which is the most popular potential energy function used for fitting spectroscopic data.

The morse potential energy function :


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