In: Chemistry
What is the significance of the coefficient of linear expansion and what role does it play in engineering design? When is it desirable to join two metals having like coefficients of linear expansion? Different coefficients?
The expansion and contraction of materials must be considered when designing large structures, when using tape or chain to measure distances for land surveys, when designing molds for casting hot material, and in other engineering applications when large changes in dimension due to temperature are expected.
Thermal expansion is also used in mechanical applications to fit parts over one another, e.g. a bushing can be fitted over a shaft by making its inner diameter slightly smaller than the diameter of the shaft, then heating it until it fits over the shaft, and allowing it to cool after it has been pushed over the shaft, thus achieving a 'shrink fit'. Induction shrink fitting is a common industrial method to pre-heat metal components between 150 °C and 300 °C thereby causing them to expand and allow for the insertion or removal of another component.
There exist some alloys with a very small linear expansion coefficient, used in applications that demand very small changes in physical dimension over a range of temperatures. One of these is Invar 36, with α approximately equal to 0.6×10−6 K−1. These alloys are useful in aerospace applications where wide temperature swings may occur.
Pullinger's apparatus is used to determine the linear expansion of a metallic rod in the laboratory. The apparatus consists of a metal cylinder closed at both ends (called a steam jacket). It is provided with an inlet and outlet for the steam. The steam for heating the rod is supplied by a boiler which is connected by a rubber tube to the inlet. The center of the cylinder contains a hole to insert a thermometer. The rod under investigation is enclosed in a steam jacket. One of its ends is free, but the other end is pressed against a fixed screw. The position of the rod is determined by a micrometer screw gauge orspherometer.
Drinking glass with fracture due to uneven thermal expansion after pouring of hot liquid into the otherwise cool glass
The control of thermal expansion in brittle materials is a key concern for a wide range of reasons. For example, both glass and ceramics are brittle and uneven temperature causes uneven expansion which again causes thermal stress and this might lead to fracture. Ceramics need to be joined or work in consort with a wide range of materials and therefore their expansion must be matched to the application. Because glazes need to be firmly attached to the underlying porcelain (or other body type) their thermal expansion must be tuned to 'fit' the body so that crazing or shivering do not occur. Good example of products whose thermal expansion is the key to their success areCorningWare and the spark plug. The thermal expansion of ceramic bodies can be controlled by firing to create crystalline species that will influence the overall expansion of the material in the desired direction. In addition or instead the formulation of the body can employ materials delivering particles of the desired expansion to the matrix. The thermal expansion of glazes is controlled by their chemical composition and the firing schedule to which they were subjected. In most cases there are complex issues involved in controlling body and glaze expansion, adjusting for thermal expansion must be done with an eye to other properties that will be affected, generally trade-offs are required.
Thermal expansion can have a noticeable effect in gasoline stored in above ground storage tanks which can cause gasoline pumps to dispense gasoline which may be more compressed than gasoline held in underground storage tanks in the winter time or less compressed than gasoline held in underground storage tanks in the summer time.[8]
Heat-induced expansion has to be taken into account in most areas of engineering. A few examples are:
Thermal expansion is the change in size of an object as its temperature changes. Normally, as the temperature increases, the size of an object also increases. Conversely, most objects shrink as the temperature drops. On a hot summer day, electrical power lines sag between power poles. The sag occurs because the wires grow longer as the temperature increases. Long bridges often have interlocking metal fingers along the joints where sections of the bridge are joined to each other. The metal fingers allow the bridge sections to expand and contract with changes in the temperature.
A relatively small number of substances contract when they are heated and expand when they are cooled. Water is the most common example. As water is cooled from room temperature to its freezing point, it contracts, like most other substances. However, just four degrees Celsius above its freezing point, it begins to expand. At its freezing point a gram of ice takes up more space than does a gram of liquid water. This change explains the fact that ice floats on top of water.