In: Chemistry
A 5.5984 g sample of soil was analyzed for lead. The sample was digested in hot perchloric acid for 5 hours, cooled, filtered to remove insoluble silicates, transferred to a 250-ml volumetric flask and diluted to the mark with distilled water. A 50.00-ml portion of the resulting solution was treated with phosphoric acid (H3PO4) forming 0.0862 g of precipitate. What was the weight % of lead?
3 Pb2+ + 2 PO43- ® Pb3(PO4)2(s)
precipitate Pb3(PO4)2 formed = 0.0862 g
Precipitate moles = mass / Molar mass of it where Pb3(PO4)2 has molar mass 811.54 g/mol
= 0.0862 / 811.54 = 0.000106
Pb2+ moles = 3 x Pb3(PO4)2 moles ( as per balanced reaction coefficents)
Pb2+ moles = 3 x 0.000106 = 0.0003186534
This is Pb2+ moles present in 50 ml part
Original 250 ml contains 5 times more Pb2+
Pb2+ moles = 5 x 0.0003186534 = 0.001593267
Pb2+ si fomed by perchoric acid
Pb moles = 0.001593267
Pb mass = moles x atomic mass of Pb
= 0.001593267 x 207.2 g/mol
= 0.33 g
weight % of Pb = (100 x Pb mass / sample mass)
= ( 100 x 0.33 /5.5984)
= 5.9 %