Question

In: Chemistry

A 147-g sample of steam at 100 ∘C is emitted from a volcano. It condenses, cools,...

A 147-g sample of steam at 100 ∘C is emitted from a volcano. It condenses, cools, and falls as snow at 0 ∘C. (For water, 80. cal (334 J) is needed to melt 1 g of ice or must be removed to freeze 1 g of water and 540 cal (2260 J) is needed to convert 1 g of water to vapor at 100 ∘C.) Part A How many kilojoules of heat were released?

Solutions

Expert Solution

Answer – We are given, mass of sample steam = 147 g , ti = 100oC, tf = 0.0oC

∆Hfus = 334 J/g , ∆Hvap = 2260 J/g

We know

Heat from the 100oC to 100oC

q1 = m*∆H vap

     = 147.0 g * 2260 J/g

     = - 332220 J

Heat from the 100.0oC to 0.0oC

q2 = m*C liq* ∆t

    = 147.0 g * 4.184 J/goC * (0.0oC –100.0oC)

     = - 61505 J

Heat from 0.0oC to 0.00oC

q3 = m*∆H fus

     = 147.0 g * 334 J/g

     = - 49098 J

Total heat q = q1+ q2+q3

                 = -332220 J -61505 J - 49098

                    = 442823 J

                  = 442.8 kJ

So, - 442.8 kJ heat were released


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