In: Chemistry
Saturated steam at 100 C is heated to 400 C. Use the steam table to determine the required heat input if continuous stream flowing at 150 kg/min undergoes this process at constant pressure.
ΔH + ΔEk + ΔEp = Q -Ws (eq. 7.4-15) all flowrates
ΔEk , ΔEp , W =0 ΔU = Q
H(400 degrees C, 1 atm) = 3278 kJ / kg (table B.7)
H(100 degrees C, sat'd 1 atm) = 2676 kJ / kg (table B.5)
stream in: 100 kg H2O (v)/s
100degrees C, sat'd
stream 1 out: 100 kg H2O (v)/s
400degrees C, 1 atm
also (into system): Q(kW)
Q = (100kg/s)[(3278-2676)kJ/kg](1000 J/kJ) = 6.02 x107 J/s
b) ΔU + ΔEk + ΔEp = Q -W (eq. 7.3-4)
ΔEk , ΔEp , W =0 ΔU = Q
Table B.5 → U(100 degrees C, 1 atm) = 2507 kJ/kg
V(100 degrees C, 1 atm) = 1.673 m3 / kg = V(400degrees C, Pfinal)
Interpolate in table B.7 to find P at which V = 1.673 at 400degrees C, and then interpolate again to find U at 400 degrees Cand that pressure:
V = 1.673 m3 / g → Pfinal =1.0 + 4.0[(3.11-1.673) / (3.11-0.617)] = 3.3 bar
U(400 degrees C, 3.3 bar) = 2966 kJ/kg
Q = ΔU = mΔU = 100 kg [(2966 - 2507)kJ/kg](1000J/kJ) = 4.59 x 107 J
The difference is the net energy needed to move the fluidthrough the system (flow work).
(The energy change associated with the pressure change in Part(b) is insignificant.)