Question

In: Chemistry

In the ground-state electron configuration of Fe3+, how many unpaired electrons are present?

Part A

In the ground-state electron configuration of Fe3+, how many unpaired electrons are present?
Express your answer numerically as an integer.

Part B

Build the orbital diagram for the ion most likely formed by phosphorous.
Use the buttons at the top of the tool to add orbital's in order of increasing energy, starting at the bottom with the lowest energy orbitals. Click within an orbital to add electrons.

Solutions

Expert Solution

Concepts and reason

The electrons are filled in the orbitals according to Hund's rule. It states that the pairing of electrons takes place only after all the degenerate orbitals are half-filled. If an atom loses electrons, it gets a positive charge, and if the atom gains electrons, it gets a negative charge.

Fundamentals

The ground state is the molecule's energy state when all the electrons are present in the lowest possible molecular orbitals. In an excited state, one electron goes from lower energy orbital to higher energy molecular orbital.

 

\(\mathbf{A}\)

The atomic number of Fe is 26.

It loses 3 electrons to form \(\mathrm{Fe}^{3+}\) ion.

Hence, the number of electrons in \(\mathrm{Fe}^{3+}\) is 23 . Therefore, its ground state electron configuration is,

\(1 s^{2} 2 s^{2} 2 p^{6} 3 s^{2} 3 p^{6} 3 d^{5}\)

Write the orbital configuration for the outermost \(3 \mathrm{~d}\) orbital as follows:

Hence, the number of unpaired electrons in \(\mathrm{Fe}^{3+}\) are 5 .

In the \(3 \mathrm{~d}\) subshell, there are 5 degenerate \(\mathrm{d}\) orbitals. Hence, according to Hund's rule, each orbital gets one electron and a total of 5 unpaired electrons.

 

\(\mathbf{B}\)

The most likely ion formed by phosphorous is \(\mathrm{P}^{3-}\).

The electron configuration of \(\mathrm{P}^{3-}\) is,

\(1 s^{2} 2 s^{2} 2 p^{6} 3 s^{2} 3 p^{6}\)

The orbital diagram for \(\mathrm{P}^{3-}\) is as follows:

The atomic number of phosphorous is 15. Its electron configuration is,

\(1 s^{2} 2 s^{2} 2 p^{6} 3 s^{2} 3 p^{3}\)

It needs 3 electrons to attain an inert gas configuration.

Hence, the most likely ion formed by phosphorous is \(\mathrm{P}^{3-}\).

Related Solutions

How many unpaired electrons are present in each of the following in the ground state? O...
How many unpaired electrons are present in each of the following in the ground state? O C+ C- Hg Y S Kr Br
Based on the electron configuration and number of unpaired electrons, which are diamagnetic? Electron configuration of...
Based on the electron configuration and number of unpaired electrons, which are diamagnetic? Electron configuration of Cu2+ is [Ar]3d(8)4s(2) and no. of unpaired electron is 2 Electron configuration of Mo4+ is [Kr]4d25s0 and no. of unpaired electron is 2 Electron configuration of Ce is [Xe] 4f1 5d1 6s2 and no. of unpaired electron is 2 Electron configuration of Sn is [Kr] 4d10 5s2 5p2 and no. of unpaired electron is 2 Electron configuration of V5+ is 1s2 2s2 2p6 3s2...
How many pairs of electrons are present in the valence shell of a neutral ground-state nitrogen...
How many pairs of electrons are present in the valence shell of a neutral ground-state nitrogen atom? Select one: a. 0 b. 1 c. 2 d. 3
Which element has a neon core and five valence electrons in its ground state electron configuration?
Which element has a neon core and five valence electrons in its ground state electron configuration?
Write the Slater determinant for the ground state electron configuration of Be.
Write the Slater determinant for the ground state electron configuration of Be.
How many valence electrons are there in an element with the following electron configuration? 1s2 2s2...
How many valence electrons are there in an element with the following electron configuration? 1s2 2s2 2p4 _______ has ____________ valence electrons
The electron configuration of an atom tells us how many electrons are in each orbital. For...
The electron configuration of an atom tells us how many electrons are in each orbital. For example, helium has two electrons in the 1s orbital. Therefore the electron configuration of He is 1s2 part a: What is the ground-state electron configuration of a neutral atom of nickel? Express your answer in condensed form, in order of increasing orbital energy. For example, [He]2s22p2 would be entered as [He]2s^22p^2 . part b: What is the ground-state electron configuration of the oxide ion...
Write the complete ground state electron configuration for the following (no shortcuts):
Write the complete ground state electron configuration for the following (no shortcuts): a.) Phosphorous b.) Scandium c.) Boron d.) Sodium e.) Silicon
Give the electron configuration for an element with 19 electrons. How many valence electrons does this element have?
Give the electron configuration for an element with 19 electrons. How many valence electrons does this element have?
TRUE or FALSE The element with a ground state electron configuration of 1s22s22p63s2 is an alkaline...
TRUE or FALSE The element with a ground state electron configuration of 1s22s22p63s2 is an alkaline earth metal. The element with a ground state electron configuration of [Kr]5s24d105p5 has 15 valence electrons. The ground state electron configuration for the undiscovered element 115 is [Rn]6s24f145d106p3. The ground state electron configuration for Cu is [Ar]4s13d10. If an element (abbreviated X) has a ground state electron configuration of [Ne]3s23p4, then the formula of the compound that X forms with magnesium is MgX. The...
ADVERTISEMENT
ADVERTISEMENT
ADVERTISEMENT