Question

In: Chemistry

Prepare a flowchart for the separation of Pb2+, Zn2+, Ba2+, Mn2+, and Al3+ .

Prepare a flowchart for the separation of Pb2+, Zn2+, Ba2+, Mn2+, and Al3+
.

Solutions

Expert Solution

Pb2+

Lead (/l?d/) is a chemical element in the carbon group with symbol Pb (from Latin: plumbum) and atomic number 82. Lead is a soft,malleable and heavy post-transition metal. Metallic lead has a bluish-white color after being freshly cut, but it soon tarnishes to a dull grayish color when exposed to air. Lead has a shiny chrome-silver luster when it is melted into a liquid. It is also the heaviest non-radioactive element

Lead is used in building construction, lead-acid batteries, bullets and shot, weights, as part of solders, pewters, fusible alloys, and as a radiation shield. Lead has the highest atomic number of all of the stable elements, although the next higher element, bismuth, has one isotope with a half-life that is so long (over one billion times the estimated age of the universe) that it can be considered stable. Lead's four stable isotopes have 82 protons, a magic number in the nuclear shell model of atomic nuclei. The isotope lead-208 also has 126 neutrons, another magic number, and is hence double magic, a property that grants it enhanced stability: lead-208 is the heaviest known stable isotope.

  Zn2+

In enzymology, a Zn2+-exporting ATPase is an enzyme that catalyzes the chemical reaction

ATP + H2O + Zn2+in ADP + phosphate + Zn2+out

The 3 substrates of this enzyme are ATP, H2O, and Zn2+, whereas its 3 products are ADP, phosphate, and Zn2+.

This enzyme belongs to the family of hydrolases, specifically those acting on acid anhydrides to catalyse transmembrane movement of substances. The systematic name of this enzyme class is ATP phosphohydrolase (Zn2+-exporting). Other names in common use include Zn(II)-translocating P-type ATPase, P1B-type ATPase, and AtHMA4.

Ba2+

Barium is a chemical element with symbol Ba and atomic number 56. It is the fifth element in Group 2, a soft silvery metallicalkaline earth metal. Because of its high chemical reactivity barium is never found in nature as a free element. Its hydroxide was known in pre-modern history as baryta; this substance does not occur as a mineral, but can be prepared by heating barium carbonate.

Mn2+

Manganese is a chemical element with symbol Mn and atomic number 25. It is not found as a free element in nature; it is often found in combination with iron, and in many minerals. Manganese is a metal with important industrial metal alloy uses, particularly instainless steels.

Historically, manganese is named for various black minerals (such as pyrolusite) from the same region of Magnesia in Greece which gave names to similar-sounding magnesium, Mg, and magnetite, an ore of the element iron,

Al3+

Aluminium (or aluminum; see spelling differences) is a chemical element in the boron group with symbol Al and atomic number 13. It is a silvery white, soft, nonmagnetic, ductile metal. Aluminium is the third most abundant element (after oxygen and silicon), and the most abundant metal in the Earth's crust. It makes up about 8% by weight of the Earth's solid surface. Aluminium metal is so chemically reactive that native specimens are rare and limited to extreme reducing environments. Instead, it is found combined in over 270 different minerals. The chief ore of aluminium is bauxite.


Related Solutions

Draw a flow diagram that summarizes the separation of the cations in these unknown: Pb2+, Mn2+,...
Draw a flow diagram that summarizes the separation of the cations in these unknown: Pb2+, Mn2+, Bi3+, Ba2+, Cu2+, Mg2+. At each step, give the correct chemical form of the cation(s) present. Alsdo indicate observed colors of precipitates and supernatants.
Qualitative scheme for seperation of ions Ag, Pb2+, Fe3+, Cu2+, Al3+, Mn2+, Ni2+, Ba
Qualitative scheme for seperation of ions Ag, Pb2+, Fe3+, Cu2+, Al3+, Mn2+, Ni2+, Ba
A voltaic cell consists of an Mn/Mn2+ half-cell and a Pb/Pb2+ half-cell. Calculate [Pb2+] when [Mn2+]...
A voltaic cell consists of an Mn/Mn2+ half-cell and a Pb/Pb2+ half-cell. Calculate [Pb2+] when [Mn2+] is 2.7 M and Ecell = 0.35 V.
design a seperation scheme for group of cations Al3+,Ba2+,Cu2+,Ni2+
design a seperation scheme for group of cations Al3+,Ba2+,Cu2+,Ni2+
Balance the reaction in acidic solution. MnO4- + Al ----> Mn2+ + Al3+
Balance the reaction in acidic solution. MnO4- + Al ----> Mn2+ + Al3+
Design a separation scheme to separate cations, Al3+, Cu2+, Ni2+, Ag+.
Design a separation scheme to separate cations, Al3+, Cu2+, Ni2+, Ag+.
Ba2+ and Pb2+ have similar ionic radii. Explain any differences you expect in the properties and...
Ba2+ and Pb2+ have similar ionic radii. Explain any differences you expect in the properties and structure of BaCl2 and PbCl2.
ZnCl2 (aq) + Al (s) ---- Zn(s) + AlCl3 (aq) [Al3+] = 0.8 M    [Zn2+] =...
ZnCl2 (aq) + Al (s) ---- Zn(s) + AlCl3 (aq) [Al3+] = 0.8 M    [Zn2+] = 1.3M Zn2+(aq) +2e- ---Zn(s)    -0.76V Al3+(aq) + 3e- --- Al (s)    -1.66V Balance the equation above. Give the equation for the reaction quotient(Q) and solve for it. Are there units for (Q)? Solve for the standard potential for the cell (EO cell) at 295K. First give equation. Solve the Nernst equation for this cell at 295K.
Suppose a solution contains 0.28 M Pb2 and 0.46 M Al3 . Calculate the pH range...
Suppose a solution contains 0.28 M Pb2 and 0.46 M Al3 . Calculate the pH range that would allow Al(OH)3 to precipitate but not Pb(OH)2. The Ksp values for Al(OH)3 and Pb(OH)2 can be found here.
Suppose a solution contains 0.22 M Pb2 and 0.49 M Al3 . Calculate the pH range...
Suppose a solution contains 0.22 M Pb2 and 0.49 M Al3 . Calculate the pH range that would allow Al(OH)3 to precipitate but not Pb(OH)2. The Ksp values for Al(OH)3 and Pb(OH)2 can be found here.
ADVERTISEMENT
ADVERTISEMENT
ADVERTISEMENT