In: Chemistry
For a parallel reaction A goes to B with rate constant k1 and A goes to C with rate constant k2, you determine that the activation energies are 24.6 kJ/mol for k1 and 116.4 kJ/mol for k2. If the rate constants are equal at a temperature of 318 K, at what temperature (in K) will k1/k2 = 2?
Arrhenius' equation gives the dependence of the rate constant
of a
chemical reaction on the absolute temperature
(in kelvin), where
is the
pre-exponential factor (or simply the prefactor),
is the
activation energy, and
is the universal gas
constant (

For the reaction 1:
,
the rate constant
is given by the
following equation:



For the reaction 2:
,
the rate constant
is given by the
following equation:



At T=318 K:






If

with

