Question

In: Chemistry

Benzene has a ΔHvap = 33.90 kJ/mol and a ΔSvap = 96.4 J/mol-K. What is the...

Benzene has a ΔHvap = 33.90 kJ/mol and a ΔSvap = 96.4 J/mol-K. What is the vaporization temperature of Benzene in Celsius?

Solutions

Expert Solution

Vaporization temperature, Tvap = ΔHvap / ΔSvap

Where Tvap is Vaporization themperatue in kelvin

Given ΔHvap = 33.90 kJ/mol

                   = 33.90x103 J/mol

       ΔSvap = 96.4 J/(mol-K)

Plug the values we get Tvap = ΔHvap / ΔSvap

                                        = (33.90x103 J/mol) / (96.4 J/(mol-K) )

                                        = 351.6 K

                                        = 351.6 - 273 oC

                                        = 78.6 oC

Therefore the vaporization temperature of Benzene is 78.6 oC


Related Solutions

Cgas = 1.3 J/g×K    Hvap = 38.56 kJ/mol    Cliq = 2.3 J/g×K      Hfus = 5.02 kJ/mol   ...
Cgas = 1.3 J/g×K    Hvap = 38.56 kJ/mol    Cliq = 2.3 J/g×K      Hfus = 5.02 kJ/mol    Csolid = 0.97 J/g×K      Condensation Temp = 78.0oC               Freezing Pt = -114.0oC Calculate the amount of heat required toconvert 92.6 mL of ethanol, C2H6O, from 110.0oC to -98.0oC.
For a hypothetical reaction, ΔrHθ = 89.1 kJ/mol and ΔrSθ = 364 J/mol/K. What is the...
For a hypothetical reaction, ΔrHθ = 89.1 kJ/mol and ΔrSθ = 364 J/mol/K. What is the total standard entropy of the reaction, ΔrStotθ, at 343 K?
Estimate Keq for the following equilibria at 350 K. R = 8.3145 J/(mol*K). Substance ΔHo(kJ/mol) So(J/(mol*K))...
Estimate Keq for the following equilibria at 350 K. R = 8.3145 J/(mol*K). Substance ΔHo(kJ/mol) So(J/(mol*K)) SnO2(s) -577.6 49.0 H2(g) 0 130.680 CO(g) -110.5 197.7 Sn(s, white) 0 51.2 H2O(l) -285.83 69.95 Fe(s) 0 27.3 Fe3O4(s) -1118.4 146.4 Correct answer. Correct. SnO2(s) + 2H2(g) ⇄ Sn(s, white) + 2H2O(l) The number of significant digits is set to 2; the tolerance is +/-3% LINK TO TEXT Incorrect answer. Incorrect. 3Fe(s) + 4H2O(l) ⇄ Fe3O4(s) + 4H2(g) Entry field with incorrect answer...
A reaction has and △H°298 = 151 kJ/mol and △S°298 = 286 J /mol K at...
A reaction has and △H°298 = 151 kJ/mol and △S°298 = 286 J /mol K at 298 K. Calculate △G in kJ/mol.
Given the data: PbO(s), Df Hq = -217.3 kJ mol–1, Sq = +68.7 J mol–1 K–1...
Given the data: PbO(s), Df Hq = -217.3 kJ mol–1, Sq = +68.7 J mol–1 K–1 PbO2(s), Df Hq = -277.0 kJ mol–1, Sq = +68.6 J mol–1 K–1 O2(g), Df Hq= 0.00 kJ mol–1, Sq = +205 J mol–1 K–1 calculate the standard free energy change, DrGq, for the reaction: PbO(s) + ½ O2(g) ® PbO2(s) Select one: a. +1.45 kJ mol–1 b. –29.1 kJ mol–1 c. –68.3 kJ mol–1 d. –90.3 kJ m
The reaction C4H8(g)⟶2C2H4(g)C4H8(g)⟶2C2H4(g) has an activation energy of 262 kJ/mol.262 kJ/mol. At 600.0 K,600.0 K, the...
The reaction C4H8(g)⟶2C2H4(g)C4H8(g)⟶2C2H4(g) has an activation energy of 262 kJ/mol.262 kJ/mol. At 600.0 K,600.0 K, the rate constant, ?,k, is 6.1×10−8 s−1.6.1×10−8 s−1. What is the value of the rate constant at 765.0 K?
The value of the universal gas constant is 0.082 (L atm)/(mol K) or 8.31 J/(mol k)...
The value of the universal gas constant is 0.082 (L atm)/(mol K) or 8.31 J/(mol k) and 1.00 atm = 760 mmHg or 760 torr. When a sample of H2​​​​O​​​​​​​​​​​​2 is decomposed, 350 mL of O2 gas is collected at 20 °C and at a partial pressure of 695 torr. How many moles of O2 gas were collect The value of the universal gas constant is 0.082 (L atm)/(mol K) or 8.31 J/(mol k) and 1.00 atm = 760 mmHg...
HCl: -164.4 kJ/mol NaOH: -469.6 kJ/mol NaCl: -407.1 kJ/mol H2O: -285.9 kJ/mol If 50 mL of...
HCl: -164.4 kJ/mol NaOH: -469.6 kJ/mol NaCl: -407.1 kJ/mol H2O: -285.9 kJ/mol If 50 mL of 1.00 M HCl and 50 mL of 2.00 M NaOH are mixed, given the enthalpies of formation above, use Hess's Law to calculate the molar heat of neutralization.
The azeotrope of the benzene-cyclohexane system has a composition of 53.2 mol% benzene with a boiling...
The azeotrope of the benzene-cyclohexane system has a composition of 53.2 mol% benzene with a boiling point of 350.6 K at 101.3 kPa. At this temperature the vapour pressure of benzene (1) is 100.59 kPa and the vapour pressure of cyclohexane (2) is 99.27 kPa. Determine the activity coefficient for the solution containing 10 mol% benzene
1. A chemical reaction at 304 K has an enthalpy change (delta-H) of -73.9 kJ/mol and...
1. A chemical reaction at 304 K has an enthalpy change (delta-H) of -73.9 kJ/mol and an entropy change (delta-S) of 161.6 kJ/mol. What is its Gibbs energy change, delta-G, in kJ/mol? Give the answer to one decimal place. 2.Use the thermodynamic data in your textbook to determine the temperature below which the following reaction is spontaneous. (Give the temperature in K, to the nearest degree.) 2SO2 (g) + O2 (g) -- 2SO3 (g) 3.What is the delta-G for the...
ADVERTISEMENT
ADVERTISEMENT
ADVERTISEMENT