In: Chemistry
What is the pH of the buffer solution that contains 2.2 g of NH4Cl in 250 mL of 0.12 NH3? Is the final pH lower than the pH of the 0.12 M ammonia solution?
Calculate the concentration of NH4Cl in 250 ml solution ={2.2g *1000}/{53.5 *250} = 0.165 M
According to Henderson equation pOH = -logKb +log[conju.acid] / [base]
where Kb of ammonia solution = 1.8*10-5
pOH = - log (1.8*10-5 ) + log [0.165] /[0.12]
= 4.7448 + 0.1409= 4.88
∴pH = 14 - pOH
= 14 - 4.88
= 9.12
The pH of the solution at initial concentration pOH =√Kb * C
= √1.8*10-5 * 0.12
= 1.469*10-2
∴ pH = 14 -0.01469 = 13.985
Hence the final pH is lower than the original pH of the ammonia solution