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Aqueous silver nitrate reacts with aqueous lead (IV) acetate. Calculate the grams of each product formed,...


Aqueous silver nitrate reacts with aqueous lead (IV) acetate. Calculate the grams of each product formed, starting witb 2.001g of silver nitrate.

Solutions

Expert Solution

Given the mass of AgNO3 taken = 2.001 g

Molecular mass of AgNO3 = 169.87 gmol-1

Hence moles of AgNO3 taken = mass / molecular mass = 2.001g / 169.87 gmol-1 = 0.01178 mol

The balanced chemical equation for the reaction of silver nitrate(AgNO3) with lead(IV) acetate is

4AgNO3(aq) + Pb(CH3COO)4(aq) -- > 4 CH3COOAg(s) + Pb(NO3)4 (aq)

4 mol 1 mol 4 mol 1 mol

For the above balanced chemical reaction,

4 mol of AgNO3 forms 4 mol of CH3COOAg.

Hence 0.01178 mol of AgNO3 that will form the moles of CH3COOAg

= (0.01178 mol AgNO3) x (4 mol CH3COOAg / 4 mol AgNO3) = 0.01178 mol CH3COOAg(s)

Molecular mass of CH3COOAg(s) = 166.91 gmol-1

Hence mass of CH3COOAg(s) = 0.01178 mol x166.91 gmol-1 = 1.966 g CH3COOAg(s) (answer)

4 mol of AgNO3 forms 1 mol of Pb(NO3)4 (aq)

Hence 0.01178 mol of AgNO3 that will form the moles of Pb(NO3)4 (aq)

= (0.01178 mol AgNO3) x (1 mol Pb(NO3)4 (aq) / 4 mol AgNO3) = 0.002945 mol Pb(NO3)4 (aq)

Molecular mass of Pb(NO3)4 (aq) = 455.22 gmol-1

Hence mass of Pb(NO3)4 (aq) formed = 0.002945 mol x455.22 gmol-1 = 1.341 g Pb(NO3)4 (aq) (answer)


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