Question

In: Chemistry

8.0g of aluminum at 200?C and 21g of copper are dropped into 45cm3 of ethyl alcohol...

8.0g of aluminum at 200?C and 21g of copper are dropped into 45cm3 of ethyl alcohol at 15?C . The temperature quickly comes to 27?C.

What was the initial temperature of the copper?

Solutions

Expert Solution

Hi,

For quantity of heat gained or lost by the sample in this problem, we will be using the formula

q=mcdeltaT

Where,

q= heat gained or heat lost by the sample

m= mass of the sample

c= Specific heat of sample which is a constant at a given temperature

deltaT= change in Temperature

Assuming that: specific heat of aluminium is 0.900 J/gm.K

specific heat of copper is 0.386 J/gm.K

specific heat of ethyl alcohol is 2.4 J/gm.K

Heat given by aluminium would be

QAl= 8gm X 0.900 J/gm.K X (473K-288K) = 1332 J

Heat given by copper would be

QCu= 21gm X 0.386 J/gm.K X (T-288K) = 8.106T-2334.528 J

Mass of ethyl alcohol = Density of ethyl alcohol X volume of ethylalcohol

Mass of ethyl alcohol= 789 kg/m^3 X 0.000045 m^3 = 0.03551 kg= 35.51 gm

Heat gained by ethanol = 35.51 gm X 2.4 J/gm.K (300K-288K) = 1022.688 J

Now, Heat lost = heat gained

1332 + 8.106T-2334.528 = 1022.688

8.106T = 2025.216

T= 249.84 K or -23.15oC

This shows even copper has gained the heat

Hope this solves your query


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