In: Chemistry
8.0g of aluminum at 200?C and 21g of copper are dropped into 45cm3 of ethyl alcohol at 15?C . The temperature quickly comes to 27?C.
What was the initial temperature of the copper?
Hi,
For quantity of heat gained or lost by the sample in this problem, we will be using the formula
q=mcdeltaT
Where,
q= heat gained or heat lost by the sample
m= mass of the sample
c= Specific heat of sample which is a constant at a given temperature
deltaT= change in Temperature
Assuming that: specific heat of aluminium is 0.900 J/gm.K
specific heat of copper is 0.386 J/gm.K
specific heat of ethyl alcohol is 2.4 J/gm.K
Heat given by aluminium would be
QAl= 8gm X 0.900 J/gm.K X (473K-288K) = 1332 J
Heat given by copper would be
QCu= 21gm X 0.386 J/gm.K X (T-288K) = 8.106T-2334.528 J
Mass of ethyl alcohol = Density of ethyl alcohol X volume of ethylalcohol
Mass of ethyl alcohol= 789 kg/m^3 X 0.000045 m^3 = 0.03551 kg= 35.51 gm
Heat gained by ethanol = 35.51 gm X 2.4 J/gm.K (300K-288K) = 1022.688 J
Now, Heat lost = heat gained
1332 + 8.106T-2334.528 = 1022.688
8.106T = 2025.216
T= 249.84 K or -23.15oC
This shows even copper has gained the heat
Hope this solves your query