Write an equation for the reaction (ignoring stereochemistry)
involving the bromination of a sample of trans-cinnamic...
Write an equation for the reaction (ignoring stereochemistry)
involving the bromination of a sample of trans-cinnamic
acid(3-phenylpropenoic acid) to form 2,3-dibromo-3-phenylpropanoic
acid.
For the bromination of trans-cinnamic acid, provide
two reasons as to why pyridinium bromide
perbromide is the brominating agent of choice as opposed to
elemental bromine.
Convert 16.5 mmol pyridinium bromide perbromide to grams
Convert 300 mmol glacial acetic acid to mL.
Prelab to accompany bromination of trans-cinnamic acid
(4 pts each)
The stoichiometry of the addition is 1:1, meaning that for every
one mole of transcinnamic acid, one mole of Br2 is needed to form
the addition product. The Br2 presents as a solution in
dichloromethane solvent. This often causes problems for students
when calculating stiochiometric equivalents. The bromine solution
is 10% Br2 by volume. For instance, 100 mL of solution contains 10
mL of liquid Br2. The density of Br2...
In Stereochemistry of bromine addition to trans-Cinnamic acid
lab we acquired a melting point of which matched erythro 2
3-dibromo-3-phenylpropanoic acid. Why was the product (or products)
formed by anti- addition? explain. what evidence in the lab would
help with explaining this? thank you!
Bromination of trans-stilbene
1. Describe what problems can occur if a reaction is refluxing
too fast or slow.
2. Why is this reaction considered “green” chemistry? How is
this different from a “non-green” bromination. What are some
disadvantages to “green” chemistry?
3. Is this reaction completely “green” chemistry? Explain why
or why not. Think about the first part of question #4 to
help.
In the bromination reaction of a chalcone, trans-4-nitrochalcone
reacts with Br2/CHCl3 to produce
erythro-2,3-diBromo-3-(4-nitrophenyl)propiophenone. The product is
a racemic mixture.
a) Draw the structure of the enantiomers you form and assign R
& S to each of the stereocenters.
b) Will you see two spots on a TLC plate for your reaction
products? Why or why not?
c) Draw the structures of the products that are not formed in
the bromination reaction.
d) Is this bromination reaction stereoselective? Why or...
For the reaction; write the conventional equation, ionic
equation, and net ionic equation, when solid copper (II) hydroxide
is "dissolved" by hydrochloric acid.
Write the equation for the reaction of HSO3- with water in which
it acts like an ACID and identify the acid, base, conjugate acid,
and conjugate base. Identify the strongest acid, then write an
expression for Ka. The value of Ka at 35 degrees celsius is 1.23 x
10^-7. Draw an arrow indicating which side is favored by
equilibrium.
for each reaction described below, write the conventional
equation, ionic equation,and net ionic equation. include
designations of state or solutions in each equation.
A) Hydrogen is released when sodium reacts with water.
B) Hydroiodic acid reacts with a solution of ammonium
sulfite.
C) Solid copper (II) hydroxide is "dissolved" by hydrochloric
cid.
D) Sodium hydroxide solution is poured into a solution of cobalt
(II) chloride.
E) Calcium metal reacts with a solution of iron (II)
bromide.
F) Hydrochloric acid reacts...