Which nuclei can be anaylzed by NMR spectroscopy? (i tired just
1^H and 13^C together)(I also...
Which nuclei can be anaylzed by NMR spectroscopy? (i tired just
1^H and 13^C together)(I also tried all of them but 3^H together)(I
don't know which of these can be anazylzed by NMR spectorscopy)
1^H
2^H
3^H
12^C
13^C
Solutions
Expert Solution
NMR-Nuclear Magnetic Resonance spectroscopy which involves
transition of a nucleus from one spin state to another
The absorption of electromagnetic radiation during transition
happens only in spin-active nuclei
The nuclei having nuclear spin not equal to zero are
spin-active, when they placed in a magnetic field the transition
occurs
The nuclei with even-even ( even number of protons and even
number of neutrons) have a spin I=0,odd-odd all have integral
nuclear spin, other than zero and (odd-even or vice-versa) have
half odd integral
The nuclei having a nuclear spin (I) not equal to zero can be
spin-active. E.g: H1 ,C13.
The nuclei having a nuclear spin (I) equal to zero are not spin
active. E.g:C12 .
Although, nuclear spin plays an inevitable role in NMR, along
with it also depends on the natural abundance of the nuclei
H1(99.98%),H2(0.02%),H3(0.00%),C
12(98.89%) But I=0,C13(1.11%) I=1/2 are its
natural abundance.
Finally, with the account of natural abundance and nuclear spin
H1 ,C13 can be analysed by NMR.
H2 ,H 3 cannot be analyzed due to their
natural abundance and C12 cannot be analyzed due to spin
inactive nature.
In 19F NMR spectroscopy, the F nuclei behave just
like protons in 1H NMR spectroscopy in that they have a
nuclear spin quantum number of 1/2. How many 19F NMR
resonances do you expect for PF5? (Assume a static
structure. In other words, the axial and equatorial do NOT rapidly
scramble and change positions on the timescale of the NMR
experiment.)
1) In H NMR spectroscopy, why is the peak for a vinyl proton,
C=C-H, shifted downfield relative to that of an alkane proton,
C(sp3)-H? Be sure to use the following terms in your
answer: pi-electrons, induced magnetic field, and resonance.
2) In H NMR spectroscopy, why is the peak for a
-CH2F group shifted downfield relative to that for a
-CH2Br group? Be sure to use the following terms in your
answer: electronegative, deshielded, magnetic field, and
frequency.
Part A Table of C-13 NMR data for
1-phenylcyclohexanol using the following headings
for each compound (carbon types: CH, CH2, CH3, CH-OH, etc) Chemical
Shift (ppm) Carbon Type
Part B Table of C-13 NMR data for
1-phenylcyclohexene using the following headings
for each compound (carbon types: CH, CH2, CH3, CH-OH, etc):
Chemical Shift (ppm) Carbon Type
Give detailed explanation of the chemical Shift only and show
the carbon labeled.
Can someone explain a,b and c? The answers are correct I believe
but I just need a more clear explenation on the formulas and final
answers
If 2 cards are drawn from a well-shuffled deck of 52 playing
cards, what are the probabilities of getting
Answer:
Total no of ways of drawing 2 cards from a well-shuffled deck of
52 playing cards = 52C2 = 1326
(a) two spades;
Number of ways getting 2 spades / total number of ways...
I want to understand how this can be solved in c++. Please
send a screenshot also with your code so I can see how it is
supposed to be formatted or indented.
Instructions:
Your program will read in a file of commands. There are three
types of commands:
Warrior creates a new warrior with the specified name and
strength. Battle causes a battle to occur between two warriors.
Status lists all warriors, alive or dead, and their
strengths.
A sample...
C programming problem
I have to design an efficient algorithm which solves this
problem. Also, it needs to include time and space complexities of
this algorithm.
There is a matrix (N times N) of integers which rows and columns
are sorted in non-decreasing order.
A sorted matrix and integer M will be given and we need to find the
position(row,column) of M in this matrix. it's okay to report only
one position if there are more than one answers.
when...
Aspirin can be prepared from salicylic acid ( C 7 H 6 O 3 ),
which has a molar mass of 138.12 g/mol, and acetic anhydride ( C 4
H 6 O 3 C 4 H 6 O 3 ), which has a molar mass of 102.04 g/mol. The
density of acetic anhydride is 1.082 g/mL.
C 7 H 6 O 3 + C 4 H 6 O 3 ⟶ C 9 H 8 O 4 + C 2 H...
which of the following is an ionic compound
a. H^2s
b. NH^3
C. I^2
D. KI
e.CCL^4
2. Which element has the following electron Configuration
(Kr)5S^24D^105P^2?
A. Sn
b. Sb
c. Pb
D. Ge
E. Te
1.Which would be least useful for MRI?
A. 1- H
B. 17-O
C. 12-C
D. 23-Na
E. 31-P
2. At 1.5 T, the excess number (%) of proton spins in the low
energy state over the high energy state is most likely:
a) > 10
b) 10
c) 1
d) 0.01
e) < 0.01