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In: Chemistry

1) In H NMR spectroscopy, why is the peak for a vinyl proton, C=C-H, shifted downfield...

1) In H NMR spectroscopy, why is the peak for a vinyl proton, C=C-H, shifted downfield relative to that of an alkane proton, C(sp3)-H? Be sure to use the following terms in your answer: pi-electrons, induced magnetic field, and resonance.

2)  In H NMR spectroscopy, why is the peak for a -CH2F group shifted downfield relative to that for a -CH2Br group? Be sure to use the following terms in your answer: electronegative, deshielded, magnetic field, and frequency.

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