Question

In: Chemistry

The hydrogen atom can absorb light of wavelength 2626 nm. A)Determine the initial value of n...

The hydrogen atom can absorb light of wavelength 2626 nm.

A)Determine the initial value of n associated with this absorption.

B)Determine the final value of n associated with this absorption.

Solutions

Expert Solution

1. this page here is a great explanation and expansion of the Rydberg equation that you can use to solve this problem: http://mooni.fccj.org/~ethall/rydberg/ry...

basically, the simplification of the Rydberg equation is:
(91.1nm/?)=(1/nf-1/ni), where nf= the final quantum shell and ni=the initial quantum shell
in this case you only need to consider the left side of this equation, so 91.1nm/2626nm=0.03469. this is a perfect fit to a drop from n=6 to n=4. how did i get this? if you refer to the page that i gave you, you'll see a table of comparisons for n and 1/n^2 values. the values correspond to one another, so the value for n=1 is 1, n=2 is 0.25, etc. all you need to do is subtract the smaller 1/n^2 value from the larger until you get a value very close to the one you got by using 91.1nm/?. the quantum shells that correspond to the numbers you subtracted will the the initial and the final shells the electron is found in.


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