when the acid constants of tert-butyl alcohol and methanol are
determined in the gas phase, tertiary alcohol is found to be a
stronger acid. This result is opposite in aqueous medium. Consider
the effects of solvation to explain these different results.
Write the balanced molecular equation and net ionic equation for
the neutralization reaction between hydrochloric acid and strontium
hydroxide. Include the phase of each species.
Explain what is the difference between the experiments synthesis
of tert-butyl chloride and the synthesis of butyl chloride in terms
of: 1) Process, 2). Reaction mechanism
7. Write an equation for the reaction of the potassium soap with
hydrochloric acid, showing the structures of reactants and
products.
8. What is the solid precipitate that was formed (in Question
7)? Did the product show sudsing action? Explain the behavior.
Draw in detail the reaction mechanism for the acid
(H2SO4)-catalyzed esterification reaction between salicylic acid
and acetic anhydride to form aspirin. Please include an explanation
of the steps of the reaction mechanism.
1. Demonstrate with a detailed, stepwise mechanism using proper
arrow pushing notation, the oxidative breakdown of pyruvate through
the step that releases GTP (ATP) in the Kreb Cycle (30 pts).
draw full sn1 mechanism for a reaction that includes
2-methyl-2-propanol, n-pentanol and hydrochloric acid as the
reactants and 2-chloro-2-methylbutane and 1-chloropentane as
products.
a)Write a balanced equation for the reaction of hydrochloric
acid with sodium hydrogen carbonate (aka sodium bicarbonate).
b)How many milliliters of 0.225 M sodium bicarbonate are needed
to neutralize 12.0 mL of 0.20 M HCl? Refer to the equation you
wrote above.