Question

In: Chemistry

Using the data in the appendix of text, calculate the standard enthalpy change for each of...

Using the data in the appendix of text, calculate the standard enthalpy change for each of the following reactions:

(A)   Si(s) + 2F2(g) ⟶ SiF4(g)

(B)    2C(s) + 2H2(g) + O2(g) ⟶   CH3CO2H(l)

(C)    CH4(g) + N2(g) ⟶   HCN(g) + NH3(g)

(D)   CS2(g) + 3Cl2(g) ⟶ CCl4(g) + S2Cl2(g)

Solutions

Expert Solution

(A)   Si(s) + 2F2(g) ⟶ SiF4(g)

H0 rex = H0f products - H0 f reactant

               = -1614.9Kj -(0 +0) = -1614.9KJ

(B)    2C(s) + 2H2(g) + O2(g) ⟶   CH3CO2H(l)

     H0 rex = H0f products - H0 f reactant

                   = -484.1-(0 +0 +0 ) = -484.1KJ

(C)    CH4(g) + N2(g) ⟶   HCN(g) + NH3(g)

          H0 rex = H0f products - H0 f reactant

                             = -46.1+135.1 -(-74.9 + 0)

                             = 163.9KJ

(D)   CS2(g) + 3Cl2(g) ⟶ CCl4(g) + S2Cl2(g)

        H0 rex = H0f products - H0 f reactant

                        = -19.5-100.4-(117.2+0)

                        = -237.1Kj/mole

      

  


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