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When did you finally stoped heating Cu and sulfur mixture in chemical reaction of copper lab?...

When did you finally stoped heating Cu and sulfur mixture in chemical reaction of copper lab? Which of the following are redox reactions ?

Explain your answer on the basis of changes in oxidation number. 1. CuSO4 + 2NaOH → Cu(OH) 2 + Na 2SO4

2. 2Al + 3MgSO4 → 3Mg + Al 2(SO4)3

3. 2(NH4)3PO4 + 3Ba(NO3)2 → Ba 3(PO4)2 + 6NH4NO3

4. 2HNO3 + 3H3AsO3 → 2NO + 3H 3AsO4 + H2O

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