Question

In: Chemistry

Kc for the reaction of hydrogen and iodine to produce hydrogen iodide. H2(g) + I2(g) ⇌...

Kc for the reaction of hydrogen and iodine to produce hydrogen iodide.

H2(g) + I2(g) ⇌ 2HI(g)


is 54.3 at 430°C. Calculate the equilibrium concentrations of H2, I2, and HI at 430°C if the initial concentrations are [H2] = [I2] = 0 M, and [HI] = 0.547 M.

[H2]=

[I2]=

[HI]=

Solutions

Expert Solution

         H2(g)    +          I2(g) ⇌      2HI(g)

I         0                         0                  0.547

C        +x                       +x                -2x

E         +x                      +x                0.547-2x

                 Kc = [HI]^2/[H2][I2]

               54.3   = (0.547-2x)^2/x*x

               54.3      = (0.547-2x/x)^2

             7.37          = 0.547-2x/x

           7.37x             = 0.547-2x

                 x   = 0.0584

   [H2]    = x   = 0.0584M

[I2]       = x   = 0.0584M

[HI]      = 0.547-2x     = 0.547-2*0.0584   = 0.43M

               


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