Question

In: Chemistry

the decomposition of amonia is shown below. if kp is 1.5x103 at 400 C, what is...

the decomposition of amonia is shown below. if kp is 1.5x103 at 400 C, what is the partial pressure of amonia when the partial pressure of H2 is 0.15 atm and N2 is 0.10 atm at equilibrium?

2 NH3(g)<____> N2 (g) + 3 H2 (g)

The correct answer is 4.47x10-4 atm please and thank you

Solutions

Expert Solution

                               2 NH3(g) N2 (g) + 3 H2 (g)

Given that the equilibrium partial pressure of H2 is, pH2(g) = 0.15 atm

                 the equilibrium partial pressure of N2 is, pN2(g) = 0.10 atm

                   Equilibrium constant , Kp = 1.5 x 10 3

For the equation Equilibrium constant , Kp = ( pN2(g) x p3H2(g) ) / p2NH3(g)

p2NH3(g) =( pN2(g) x p3H2(g) ) / Kp

                                                                   = (0.10 x 0.153 ) / ( 1.5 x 10 3 )

                                                                   = 2.25x10 -7

                                                   pNH3(g) = (2.25x10 -7 )

                                                                 = 4.74x10 -4 atm

So partial pressure of ammonia is p NH3(g) = 4.74x10 -4 atm


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