Larson (1964) measured the diffusivity of chloroform in air at
298 K and 1 atm and...
Larson (1964) measured the diffusivity of chloroform in air at
298 K and 1 atm and reported its value as 0.093 cm2/s. Estimate the
diffusion coefficient by the Wilke-Lee equation and compare it with
the experimental value.
5. A sample of N2 gas at 298 K and 1 atm. The diameter of N2
molecule is d = 3.6 × 10-10 m. (1) Calculate the collisions per
second that one molecule of N2 make. (II) Calculate the mean free
path 2 in meter. 6. An ideal gas has absorbed 900 J as a heat
energy and the volume of the gas was decreased from 20 L to 10 L at
constant external pressure of 5 atm. (1) The...
1. Calculate the adiabatic flame temperature for the following
mixtures initially at 298 K: stoichiometric butane-air mixture,
stoichiometric butane-oxygen mixture, 2.0% (by volume) of butane in
air. Use enthalpies of formation and heat capacities from the NIST
Chemistry WebBook, which can be found at
http://webbook.nist.gov/chemistry/.
2) Repeat the adiabatic flame temperature calculation without the
restriction on the possible products using an online version of the
CEA calculator developed by NASA and located at
http://www.grc.nasa.gov/WWW/CEAWeb/ceaHome.htm. Compare the results
of the two...
Estimatethe total entropy change when 100.g of liquid water,
initially at 298 K and 0.50 atm,is first heated to boiling at 373 K
and 1.00atm, and the steamcollected at 1.00 atmsubsequently heated
and compressed to 500Kand20.atm. UseDHvap(at 100 ̊C, 1 atm)= 40.6
kJ/mol and the following values for the heat capacity:CP,m(H2O,l) =
75.2 J/(K mol), CP,m(H2O,g) = 35.0J/(K mol)
Liquid phenol at 298 k, 100kPa is burned with 152%
theoretical air at 295k, 100kPa. Determine the adiabatic flame
temperature. Enthalpy of liquid phenol is given as -96,232
kJ/kmol
Calculate the adiabatic flame temperature for the following
mixtures initially at 298 K: stoichiometric butane-air mixture,
stoichiometric butane-oxygen mixture, 2.0% (by volume) of butane in
air. Calculate without the
restriction on the possible products using an online version of the
CEA calculator developed by NASA and located
athttp://www.grc.nasa.gov/WWW/CEAWeb/ceaHome.htm. Compare the
results of the two calculations and explain possible
differences.
Solid magnesium reacts with aqueous hydrochloric acid, HCI, to form aqueous magnesium chloride and hydrogen, H2, gas at 298 K and 1 atm pressure. a. Write a balanced chemical equation, including phases, to describe this reaction. b. If a 1.512-g sample of magnesium is added to 0.2558 moles of hydrochloric acid, how many moles of hydrogen gas are formed? c. In an actual experiment in which the amounts of magnesium and hydrochlorie acid from part b (above) are reacted, 1.23 L of H2...
You are asked to prepare 3.4 L of a HCN/NaCNbuffer that has a pH
of 9.69 and an osmotic pressure of 1.59 atm at 298 K. What masses
of HCN and NaCN should you use to prepare the buffer? (Assume
complete dissociation of NaCN.)
Air enters a window air conditioner at 1 atm, 36oC
and 75% relative humidity (??) at a rate of 12m3/min and
it leaves as saturated air at 18oC. Part of the moisture
in the air which condenses during the process is also removed at
18oC. Determine (a) the rate of heat
(Q?) and (b) moisture removal from the air. (c)
What-if Scenario: What would the rate of heat
removal be if moist air entered the dehumidifier at 95 kPa instead...
A thin plate is suspended in air at 1 atm. with T_infinite=
15°C. Air flows on both sides of the plate where the bottom side
absorbs a uniform radiative heat flux of 1542 W/m2. The plate is
oriented parallel to the flow and the length along the flow
direction is 60 cm. Consider the plate is negligibly thin and the
width of the plate (perpendicular to the flow) is large, so that
the problem can be considered as a 2D...
1. Methane and oxygen exist in a stoichiometric mixture at 500
kPa and 298 K. They are ignited and react at constant volume.
Combustion is complete.
a. Find the heat removed from the system per kmol of fuel if the
final products are at 1500 K.
b. What is the final pressure?
c. Explain what assumptions made in this calculation are less
accurate for constant volume combustion than for the constant
pressure combustion we have studied before.
d. If the...