Question

In: Chemistry

a rock returned from the surface of the moon has a ratio of Rb87 to stable...

a rock returned from the surface of the moon has a ratio of Rb87 to stable Sr87 atomos equal to 14.45 assuming that this was all Rb87 upon the formation of the solar system, estimate the age of the solar system.

ans key:

t= 4.537*109 yr

Solutions

Expert Solution

Ans. Using the formula: ln (A0 / At) = kt            - equation 1 (equation 1 rearranged)

            Where,             

Ao = Initial amount

                        At = Amount remaining at time t

                        k = decay constant

                        t = time duration of radioactivity

Given, Radioactive 87Rb decays into stable 87Sr

            [87Rb] : [87Sr] = 14.45 : 1

Since, 87Rb decays into 87Sr, all 87Sr is derived from 87Rb. One 87Sr nucleus decays into one 87Rb nucleus. So, Total initial amount of 87Rb is equal to present [87Rb] + [87Sr]

Or, total initial [87Rb] = [87Rb] + [87Sr] = 14.45 + 1 = 15.45 -at present    ; given, [87Rb] : [87Sr] = 1: 14.45

Or, total initial [87Rb] = 15.45

Thus, [A0] = 15.45

Final (at present) [87Rb] = Initial amount – amount decayed into 78Sr

                                    = Initial amount – present amount 78Sr

                                    = 15.45 – 1.0 = 14.45

Thus, [At] = 14.45

Known: Decay constant, k for 87Rb = 1.42×10-11yr-1

Putting the values in equation 1-

            ln (15.45 / 14.45) = (1.42 × 10-11 yr-1) x t

or, 0.066914588785 = (1.42 × 10-11 yr-1) x t

or, t = (0.066914588785) / (1.42 × 10-11 yr-1) = 0.0471 x 1011 y

Hence, age of the solar system= 4.71 x 109 years.

Note: The variation might be due to decays constant value. Please cross-check the vale in your book.   


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